CHEM 2443 Chapter Notes - Chapter 5: Pentyl Group, Electronegativity, Sigma Bond

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8 Sep 2016
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Structurally, an aldehyde has one hydrogen and one carbon group attached to the carbonyl carbon, although formaldehyde has 2 hydrogen atoms (h2c=o: if 2 carbon groups (alkyl groups) are attached to the carbonyl carbon, the generic formula is. R2c=o and the molecule is called a ketone (figure 63: the functional group is the carbonyl in both groups. Chose path that gives the simplest substituents: figure 69. Cyclic ketones are possible and the carbonyl carbon is part of the ring (must be part of the ring to be considered a cyclic ketone) Carbonyl unit is part of a 7-carbon ring, a cycloheptanone. Carbonyl carbon is c1, substituents are given lowest possible numbers. For this reason, the number is omitted: substituents attached to the aldehyde chain are named in the usual manner, with the carbonyl carbon always numbered 1, figure 70. Decanal chain in purple, substituents in green. Pentyl group (on left) is abbreviated: figure 71.

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