CHEM 10052 Study Guide - Midterm Guide: Propene, Hydrogenation, Cyclooctane

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puceferret143

30 Oct 2014

School

Kent State University

Department

Chemistry

Course

CHEM 10052

Professor

All

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Document Summary

2-butene (cis or trans) isoprene sec-butylbromide adenine benzene borane (bh3) borohydride anion cycloalkanes (cyclopropane through cyclooctane) cyclohexane chair conformations (axial and equatorial positions) alkoxide anion (e. g. , ethoxide) imidazole indole meso-1,2-dimethylcyclopentane (cis) = rs. 1,3-cyclopentadiene (& its aromatic conjugate base ) pyridine sodium borohydride (ethoxyborohydride) sulfuric acid. Real lewis structures exemplifying all functional groups to date: alkane alkene alkylhalide (1 , 2 & 3 ) alcohol (1 , 2 & 3 ) iso-propyl (2e) n-butyl (1e) isobutyl (1e) sec-butyl (2e) ter-butyl (3e) All alcohols and all alkyl halides bearing the above alkyl groups ethylene glycol glycerol. Huckel"s rules (4n + 2) electrons (some of which may be unshared electrons in a given lewis resonance structure) carbocation (carbonium ion) stable carbocation transition state intermediate reaction coordinate. E = eproducts - ereactants rate of reaction (v) unimolecular reaction (rate = k1[reactant1] Functional groups in cyclic structures (e. g. , bimolecular reaction cyclohexanol; cyclopentanone): primary(1e)/secondary(2e)/tertiary(3e) carbon alkyl groups: methyl ethyl n-propyl (1e) (rate= k2[reactant1] [reactant2])

Related Questions

can someone help me answer these 12 questions using the molecule ASPIRIN:

Does your structure have any primary resonance structures? If so draw them.

Does your structure have any secondary resonance structures? If so draw them.

Draw its conjugate base and any resonance structures

Is any part of your molecule basic? If so, draw its conjugate acid and any possible resonance structures. Identify a rotatable bond in your molecule and draw a Newman projection looking down this bond.

Draw one conformer of your molecule using the Newman projection you drew above.

Draw one constitutional isomer of your molecule.

Label any double bonds as E, Z or neither (donât label double bonds in a ring)

If applicable, label any rings as cis or trans (rings made up of sp²carbons do not have cis/trans)

If you structure contains a 6-membered sp³ring, draw it in its chair conformation

Draw an enantiomer of your molecule

Draw a diastereomer of your molecule

THANK YOU FOR ANY HELP!

Classify each of the following statements as true or false:

a) To be classified as organic, a compound must be or have been part of a living organism.

b) Carbon atoms normally form four bonds in organic compounds.

c) Only an unsaturated hydrocarbon can engage in an addition reaction.

d) Members of a homologous series differ by a distinct structural unit.

e) Alkanes, alkenes, and alkynes are unsaturated hydrocarbons.

f) Alkyl groups are a class of organic compounds.

g) Isomers have the same molecular formulas but different structural formulas.

h) Cis-trans isomerism appear among alkenes but not alkynes.

i) All aliphatic hydrocarbons are unsaturated.

j) Aromatic hydrocarbons have a ring structure.

k) An alcohol has an alkyl group bonded to an oxygen atom, and an ether has two.

l) Carbonyl groups are found in alcohols and aldehydes.

m) An ester is an aromatic carbon made from the reaction of an alcohol and a carboxylic acid.

n) An amine has one, two, or three alkyl groups substituted for hydrogens in an ammonia molecule.

o) An amide has the structure of a carboxylic acid except that replaces OH in the carboxyl group.

p) A peptide linkage series arises when a water molecule forms from a hydrogen from the of one amino acid molecule an from an another amino acid molecule.