CHEM1020 Study Guide - Final Guide: Substituent

78 views3 pages

magentasnake323

6 Nov 2018

School

University of Newcastle

Department

Chemistry

Course

CHEM1020

Professor

Sally Fell

For unlimited access to Study Guides, a Grade+ subscription is required.

Document Summary

Common names: the alkyl groups bonded to nitrogen are listed in alphabetical order in one word ending in the suffix amine. Systematic names: the parent chain is the longest chain that contains the -nh2 group and numbered in the direction that gives the -nh2 group the lower number. The suffix e of the parent alkane is changed to amine. 2o and 3o amines are named as n -substituted amines. For unsymmetrical amines, the largest group is taken as the parent amine; the smaller groups are named and their location indicated by the prefix. Other functional groups are of higher precedence than the nh2 group and accordingly, it is named as an amino- substituent. Both 1o and 2o amines form intermolecular hydrogen bonds. All amines form hydrogen bonds with water; most low mw amines are completely soluble and high mw amines are moderately or insoluble in water.

Related Questions

QUESTION 1

In naming branched alkanes, we name alkane branches of different names in _________ order.

	a.	alphabetical
	b.	numeric
	c.	size
	d.	none

QUESTION 2

A 10 carbon hydrocarbon with a 1 carbon group at the 2nd and 4th carbons, a 3 carbon group at the 5th carbon and a 2 carbon group at the 4th carbon would be named ______________.

	a.	5-propyl-4-ethyl-2,4-dimethyldecane
	b.	4-ethyl-2,4-dimethyl-5-propyldecane
	c.	none
	d.	2,4-dimethyl-4-ethyl-5-propyldecane

QUESTION 3

In naming alkanes, the longest chain is named using a prefix and the suffix _________.

	a.	none
	b.	-yl
	c.	-ane
	d.	-ate

QUESTION 4

In naming branched alkanes, the ___________ chain is given the name of the corresponding n-alkane.

	a.	main
	b.	side
	c.	none
	d.	first

QUESTION 5

In drawing structures from a name, the first step is to ___________.

	a.	draw the carbon skeleton
	b.	add the hydrogens
	c.	none
	d.	draw the branch skeletons

QUESTION 6

In naming branched alkanes, we use __________ to separate the name of the branch from its number.

	a.	an apostrophe
	b.	none
	c.	a dash
	d.	a comma

QUESTION 7

Alkanes are classified as ________ hydrocarbons.

	a.	unsaturated
	b.	transsaturated
	c.	saturated
	d.	none

QUESTION 8

The prefix but- refers to a hydrocarbon with __________ carbons.

	a.	three
	b.	two
	c.	four
	d.	one

QUESTION 9

Alkanes fall into two classifications, __________ alkanes and branched alkanes.

	a.	none
	b.	neat
	c.	normal
	d.	linear

QUESTION 10

The prefix hex- refers to a hydrocarbon with _________ carbons.

	a.	eight
	b.	four
	c.	two
	d.	six

Classify each of the following statements as true or false:

a) To be classified as organic, a compound must be or have been part of a living organism.

b) Carbon atoms normally form four bonds in organic compounds.

c) Only an unsaturated hydrocarbon can engage in an addition reaction.

d) Members of a homologous series differ by a distinct structural unit.

e) Alkanes, alkenes, and alkynes are unsaturated hydrocarbons.

f) Alkyl groups are a class of organic compounds.

g) Isomers have the same molecular formulas but different structural formulas.

h) Cis-trans isomerism appear among alkenes but not alkynes.

i) All aliphatic hydrocarbons are unsaturated.

j) Aromatic hydrocarbons have a ring structure.

k) An alcohol has an alkyl group bonded to an oxygen atom, and an ether has two.

l) Carbonyl groups are found in alcohols and aldehydes.

m) An ester is an aromatic carbon made from the reaction of an alcohol and a carboxylic acid.

n) An amine has one, two, or three alkyl groups substituted for hydrogens in an ammonia molecule.

o) An amide has the structure of a carboxylic acid except that replaces OH in the carboxyl group.

p) A peptide linkage series arises when a water molecule forms from a hydrogen from the of one amino acid molecule an from an another amino acid molecule.

r) Chain-growth polymers are made a reaction that gives off water a second product.

s) Nylon is an example of a step-growth condensation polymer.

sangriacicada137

For each of the following, fill in the blank with the correct response. All of these fill-in-the-blank problems pertain to material covered in the sections on alkanes, alkenes and alkynes, aromatic hydrocarbons, and hydrocarbon derivatives.

a. The first "organic" compound to be synthesized in the laboratory, rather than being isolated from nature, was _ _ _ _ _, which was prepared from _ _ _ _ _.

b. An organic compound whose carbon-carbon bonds are all single bonds is said to be _ _ _ _ _.

c. The general orientation of the four pairs of electrons around the carbon atoms in alkanes is _ _ _ _ _.

d. Alkanes in which the carbon atoms form a single unbranched chain are said to be _ _ _ _ _ alkanes.

e. Structural isomerism occurs when two molecules have the same number of each type of atom but exhibit a different arrangement of the _ _ _ _ _ between those atoms.

f. The systematic names of all saturated hydrocarbons have the ending _ _ _ _ _ added to a root name that indicates the number of carbon atoms in the molecule.

g. For branched hydrocarbon, the root name for the hydrocarbon comes from the number of carbon atoms in the _ _ _ _ _ continuous chain in the molecule.

h. The positions of substituents along the hydrocarbon framework of a molecule are indicated by the _ _ _ _ _ of the carbon atom to which the substituents are attached.

i. The major use of alkanes has been in _ _ _ _ _ reactions, as a source of heat and light.

j. With very reactive agents, such as the halogen elements, alkanes undergo _ _ _ _ _ reactions, whereby a new atom replaces one or more hydrogen atoms of the alkane.

k. Alkenes and alkynes are characterized by their ability to undergo rapid, complete _ _ _ _ _ reactions, by which other atoms attach themselves to the carbon atoms of the double or triple bond.

l. Unsaturated fats may be converted to saturated fats by the process of _ _ _ _ _.

m. Benzene is the parent member of the group of hydrocarbons called _ _ _ _ _ hydrocarbons.

n. An atom or group of atoms that imparts new and characteristic properties to an organic molecule is called a _ _ _ _ _ group.

o. A _ _ _ _ _ alcohol is one in which there is only one hydrocarbon group attached to the carbon atom holding the hydroxyl group.

p. The simplest alcohol, methanol, prepared industrially by the hydrogenation of _ _ _ _ _.

q. Ethanol is commonly prepared by the _ _ _ _ _ of certain sugars by yeast.

r. Both aldehydes and ketones contain the _ _ _ _ _ group, but they differ in where this group occurs along the hydrocarbon chain.

s. Aldehydes and ketones can be prepared by _ _ _ _ _ of the corresponding alcohol.

t. Organic acids, which contain the _ _ _ _ _ group, are typically weak acids.

u. The typical sweet-smelling compounds called _ _ _ _ _ result from the condensation reaction of organic acid with an _ _ _ _ _.

rubyzebra85

CHEM1020 Study Guide - Final Guide: Substituent

Document Summary

Get access

Related textbook solutions

Chemistry: Structure and Properties

Basic Chemistry

Principles of Chemistry Molecular Approach

Principles of Chemistry Molecular Approach

Chemistry: Structure and Properties

Chemistry: A Molecular Approach

Chemistry: A Molecular Approach

Principles of Chemistry: A Molecular Approach

Chemistry: The Central Science

Related Documents

CHEM1020 Study Guide - Final Guide: Parent Structure, Covalent Bond, Hydrogen Bond

CHEM 102 Lecture Notes - Lecture 21: Aromatic Amine, Cycloalkane, Heterocyclic Compound

Chemistry 1027A/B Chapter Notes - Chapter 10: Aromatic Amine, Lone Pair, Orbital Hybridisation

Related Questions