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- Identify each substituent as axial or equatorial, and tell whether the conforma-
tion shown is the more stable or less stable chair form (gray -C, yellow-green -Cl, ivory -H).
- Identify each substituent as axial or equatorial, and tell whether the conforma-
tion shown is the more stable or less stable chair form (gray -C, yellow-green -Cl, ivory -H).
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Related questions
Name the above compound, identify each substitutent as axial or equatorial, and tell whether the conformation shown is the more stable or less stable form.
Omit customary italics from your name.
Substitutents R1 and R2 are designated in the order they appear in the IUPAC name. Axial/equatorial strain energy increments are available in the table below.
The IUPAC name is
Position of R1 _________axial or equatorial. Position of R2 _________axial or equatorial
The conformation shown is the _________more stable or less stable.
Substituent (solvent) | kJ/mol | kcal/mol | Substituent (solvent) | kJ/mol | kcal/mol |
---|---|---|---|---|---|
-CH3 | 7.3 | 1.7 | -CO2CH2CH3 | 5.0 | 1.2 |
-CH2CH3 | 7.5 | 1.8 | -Cl | 2.5 | 0.6 |
-CH(CH3)2 | 9.2 | 2.2 | -Br | 2.5 | 0.6 |
-C(CH3)3 | 20 | 4.8 | -CN, cyano | 0.8 | 0.2 |
phenyl | 11.7 | 2.8 | -OH (cyclohexane) | 2.5 | 0.6 |
cyclohexyl | 9.2 | 2.2 | -OH (isopropanol) | 4.0 | 1.0 |
-CH=CH2 | 6.2 | 1.5 | -OCH3 | 2.5 | 0.6 |
-CCH, ethynyl | 2.1 | 0.5 | -NH2 (toluene) | 5.2 | 1.2 |
-CHO | 3.0 | 0.7 | -NH2 (CH3OCH2CH2OH/H2O) | 7.1 | 1.7 |
-COCH3 | 5.1 | 1.2 | -NO2 | 4.8 | 1.1 |
-CO2H | 5.9 | 1.4 |
Energy difference between axial and equatorial conformers.
Solvent specified when the increment is solvent dependent.