CHEM 301 Lecture Notes - Lecture 5: Chemical Polarity, Euclidean Vector, Neopentane

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29 Jan 2018
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Summary of hybridization: the number of hybrid orbitals is always the same as the total number of s and p orbitals hybridized. Rotation of single bonds- is possible: ethane is composed of two methyl groups bonded by the overlap of their sp3 hybrid orbitals, there is free rotation along all single bonds (all c-c single bonds and all c-h bonds) In order for a double bond to exhibit cis and trans isomers, the 2 groups on the same carbon must not be identical. Intermolecular forces (imf: forces that hold together in the condensed phases. Dipole-dipole forces: d-d forces are attractive imf resulting from the attraction of positive and negative ends of the dipoles of polar molecules, this attraction must be overcome when solids melt or liquids vaporize. Imf: hydrogen bonding: h-bonding is a strong d-d attraction between specific atoms of neighboring molecules (or same molecule if geometrically applicable)

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