CHEM 1007 Lecture Notes - Lecture 1: Propene, Electronegativity, Bromine

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rosejackal373

22 May 2016

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The physical and chemical properties of an organic compound depend on the number and arrangement of carbon atoms with the molecule, and the functional group. The larger the number of carbon atoms, larger molecule, larger van der waal"s forces so higher melting & boiling points and viscosity. Molecules with no branching have a higher surface area so larger van der waals. A functional group is a specific atom or group of atoms that confer certain physical and chemical properties onto the molecule. Organic compounds with the same functional group but different number of carbon atoms belong to the same homologous series. Isomers are molecules with the same molecular formula but different structural formulas. Alkanes can form chloroalkanes from free radical substitution: ch4 +cl2 -> ch3cl + hcl. A substitution reaction is where an atom or group of atoms on the organic molecule is directly replaced by another.

Related Questions

Part F: some functional groups

Classify each of the following statements as true or false:

a) To be classified as organic, a compound must be or have been part of a living organism.

b) Carbon atoms normally form four bonds in organic compounds.

c) Only an unsaturated hydrocarbon can engage in an addition reaction.

d) Members of a homologous series differ by a distinct structural unit.

e) Alkanes, alkenes, and alkynes are unsaturated hydrocarbons.

f) Alkyl groups are a class of organic compounds.

g) Isomers have the same molecular formulas but different structural formulas.

h) Cis-trans isomerism appear among alkenes but not alkynes.

i) All aliphatic hydrocarbons are unsaturated.

j) Aromatic hydrocarbons have a ring structure.

k) An alcohol has an alkyl group bonded to an oxygen atom, and an ether has two.

l) Carbonyl groups are found in alcohols and aldehydes.

m) An ester is an aromatic carbon made from the reaction of an alcohol and a carboxylic acid.

n) An amine has one, two, or three alkyl groups substituted for hydrogens in an ammonia molecule.

o) An amide has the structure of a carboxylic acid except that replaces OH in the carboxyl group.

p) A peptide linkage series arises when a water molecule forms from a hydrogen from the of one amino acid molecule an from an another amino acid molecule.

r) Chain-growth polymers are made a reaction that gives off water a second product.

s) Nylon is an example of a step-growth condensation polymer.

sangriacicada137

1.Structural isomer refers to organic compound that have the same molecular formula but different structure (bonding pattern is different). This problem is designed to guide you to explore structure isomer.

(a)Go ahead and write Lewis structure for butane (C₄H₁₀). You may draw four C atoms connect straight as like in train.

(b)In the above structure, four C atoms are connected straight in a line. If you move one C atom to the side (like 3 C atoms in a line, one connected to the middle C atom), after you supply all the H atoms to make all the C atoms saturated with 4-bonds each. Will the molecular formula for your structure drawn be different from butane?

( c) Structures you obtained in (a) and (b) are an example of structural isomers. What kind of name we can give to structure in (b) so we can differentiate it from structure in (a)?

2.Alkane is the basic building block of organic compound. We often write alkane chain as a group R. On this basic chain, we can add different functional group, like âOH for alcohol, -COOH for carboxylic acid.

(a)Methanol refers to CH₃OH. Ethanol refers to CH₃CH₂OH. Draw the Lewis structure for these two compounds.

(b) If you have a straight alkane chain, where does âOH group can be attached? How do you name it so you can know where âOH group is attached?

3. Give the Lewis structure for CH₃COOH. Give its systematic name and common name.

4. Ester refers to two alkane chains connected through a single O atom. Write the Lewis structure for this simplest kind of ester: CH₃OCH₃. Find its name and some common use.

5. Benzene molecular formula is C₆H₆. The six carbon atoms are connected to form a ring (hexagon). Draw the Lewis structure for C₆H₆. Do you think the six bond lengths between C-C atoms should be same or not according to your drawn Lewis structure?

CHEM 1007 Lecture Notes - Lecture 1: Propene, Electronegativity, Bromine

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