CHEM 2261 Study Guide - Quiz Guide: Sodium Amide, Acetic Acid, Allyl Group
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You will be given a table of electronegativities, an abbreviated periodic table and a list of reagents. Synthesize alkynes via consecutive e2 eliminations of vic-dihalides or gem-dihalides (notes pg. Hydrogenation of alkenes via syn addition of h2/metal catalyst such as pt, pd, or ni/c (notes pg. Form a sodium acetylide from a terminal alkyne reacted with nanh2. Then react this strong nucleophile with an alkyl halide via a sn2 reaction. (notes pg. Know electrophilic addition (ea) reactions of alkenes with different reagents including markovnikov or anti-markovnikov, carbocation mechanism and thus possible rearrangement, and stereochemistry of the products formed. (notes pgs. 176-177 to learn products and 179 to learn stereochemistry of products) Know oxidation of alkenes to form syn 1,2-dihydroxylation products using either kmno4, naoh, h2o (cold) or 1) oso4, pyridine 2) nahso3, h2o (notes pg. Know oxidative cleavage of alkenes using either 1) kmno4, naoh, h2o (heat) 2) h3o+ or.
