6767 Chapter Notes - Chapter organic chemistry alcohol phenol: Chch-Dt, Aliphatic Compound, Molecular Geometry

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Aromatic hydroxy derivatives ( i ) ( i i ) ( a ) Hydroxy derivatives in which oh is directly attached to sp3 c (alcoholic compounds). Hydroxy derivatives in which oh is directly attached to sp2 c or benzene ring (phenolic compounds). Classificat ion accordi ng to number of oh groups : (i) Classificat ion accordi ng to nature of carbon : (i) (ii) (i) Str ucture of alcohol : p or 1 alcohol ch3ch2 oh s or 2 alcohol (ch3)2ch oh t or 3 alcohol (ch3)3c oh. "o" atom of oh group) is sp3 hybridised. The central "o" atom is also in sp3 state of hybridisation. In sp3 hybridisation of o - 2s2,2px orbitals hybridised to form sp3 orbitals. In these four orbitals two containing one electron each and two containing two electrons each. Orbitals containing two electrons do not take part in bonding.

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