6767 Chapter : alkyl hallide aryl hallide

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Compounds derived from hydrocarbons by replacement of one or more h-atoms by corresponding no. of halogen atoms are known as halogen derivatives. On the basis of nature of hydrocarbon from which they are obtained, hydrocarbon derivatives can be classified as : Tertiary halide (a) alkyl halides : halogen derivative of alkanes. (b) alkenyl halides : halogen derivative of alkenes. (c) alkynyl halides : halogen derivative of alkynes (d) aryl halides : halogen derivative of arenes (aromatic) Alkyl halides : they are further classified on the basis of halogen atoms introduced in the molecule. e. g. ( i ) Mono halides: these involves replacement of one h-atom by halogen atom. Ch 3ch 2br ethyl bromide (bromo ethane) ( i i ) Dihalides : replacement of two h-atom by halogen atoms. Trihalides : replacement of three h-atoms by halogen atoms. General formula - cnh2n-1x3. ( i i i ) Example : chx3 trihalo methane or haloform ( i v )

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