CHEM 1127Q Lecture Notes - Lecture 28: Joule, Phase Diagram, Triple Point
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Liquids and solids are very different from gas: liquids and solids are essentially in molecular contact with each other. Ideal gas law assumed that intermolecular collisions didn"t matter. As long as there is liquid in the container there is an amount of vapor in the container equal to the vapor pressure. It is in a room with a volume of 100,000 l at. On the day after the pool was completed you filled it with exactly 10,000 l of water. The vapor pressure of water at 25oc is 24mm hg. Air in the room was dry before the water was in it. Room has 100,000 l of air & 10,000 l of water. Some of the water will pop off and form water vapor. Pv = nrt n = moles of water. R = 0. 0821 l atm / mole k. P = 24 mm hg /760mm hg per atm n will = 129. 07 moles h2o x 18 g/moles.
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