CHEM102 Lecture Notes - Lecture 3: Rate Equation, Bromine

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CHEM102 Full Course Notes
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CHEM102 Full Course Notes
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An integrated rate law is an equation that expresses the concentrations of reactants or products as a function of time. R = k[a] (this will be given in the question) Integrated rate law= ln[a] = ln[a]o kt. The graph of ln[a] against time is always a straight line if the reaction is first order only. Half- life: time taken for initial concentration to decrease to half: half-life of a first order reaction does not depend on concentration, whatever the initial concentration, the half life is always the same. Graph showing half-life of a 1st order reaction http://www. chem. purdue. edu/gchelp/howtosolveit/kinetics/kineticsart/a_vs_t_1st_order. jpg. Integrated rate law= [a] = [a]o kt. The rate depends on the pt plate, and not n2o. If the pt plate is saturated, increasing the concentration of n2o will not increase the rate of reaction. Half-life: time taken for initial concentration to decrease to half. [a] = [a]o kt: half- life of a zero-order reaction depends on concentration.

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