CHEM 24112 Chapter Notes - Chapter 9: Copper(Ii) Sulfate, Orthogonal Group, Salt Metathesis Reaction

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Homework 9.3: Limiting Reactants

1. For each of the following unbalanced reactions, suppose exactly 5.00 g of each reactant is taken.

Determine which reactant will be limiting, and also determine what mass of the excess reagent will

remain after the limiting reactant is consumed.

a. Na2B4O7(s) + H2SO4(aq) + H2O(l)  H3BO3(s) + Na2SO4(aq)

b. CaC2(s) + H2O(l)  Ca(OH)2(s) + C2H2(g)

c. NaCl(s) + H2SO4(l)  HCl(g) + Na2SO4(s)

d. SiO2(s) + C(s)  Si(l) + CO(g)

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Homework 9. 3: limiting reactants: for each of the following unbalanced reactions, suppose exactly 5. 00 g of each reactant is taken. Show by calculation which reactant is the limiting reagent. Both reactants are colorless when the solutions are freshly prepared, but the solid product is bright yellow so the process demonstrates a double displacement very effectively. Suppose a solution containing 1. 25 g of ki is combined with a solution containing 2. 42 g of pb(no3)2. What mass of pbi2 would result: the copper (ii) ion in a copper (ii) sulfate solution reacts with potassium iodide to produce the triiodide ion, i3 sample. Cuso4(aq) + ki(aq) cui(s) + ki3(aq) + k2so4(aq). If 2. 00 g of ki is added to a solution containing 0. 525 g of cuso4, calculate the mass of each product produced. This reaction is commonly used to determine how much copper is present in a given: silicon carbine, sic, is one of the hardest materials known.

Related Questions

CHM111

Q1. Which of the following contains the MOST atoms? You shouldn't need to do a calculation here.

A) 10.0 g Ne

B) 10.0 g He

C) 10.0 g Ar

D) 10.0 g Kr

E) 10.0 g Mg

Q2. How many atoms are present in 0.23 moles of Calcium?

Q3. How many atoms are present in 5.6 mg of Silicon?

Q4. How many grams of iodine do 5.6 x 10²⁵ atoms of iodine represent?

Q5. Balance the following Chemical Equations:

_____ CaC₂(s) + _____H₂O(l) ? _____ Ca(OH)₂(aq) + _____ C₂H₂(g)

_____ P₄O₁₀ + _____ H₂O? ______ H₃PO₄

___ C₃H₈O₃ + ___ O₂ ? ___ CO₂ + ___ H₂O

_____ C₄H₁₀(l) + _____ O₂(g) ? _____ CO₂(g) + _____ H₂O(g)

___ Al + ___ N₂ ? ___ Al₂N₃

___ NaN₃ ? ___ Na + ___ N₂

___ C₃H₅N₃O₉ ? ___ CO₂ + ___ N₂ + ___ H₂O + ___ O₂

Q6. Calculate the percent composition of each element in Al(NO₃)₃

Q7. A 65.0 g sample of a pure compound containing only Nickel, Oxygen and Carbon is found to contain 22.36 g Nickel and 18.27 g Carbon. What is the empirical formula of compound?

Q8. Determine the Empirical formula and Molecular formula of a compound that contains: 65.4% C, 9.15% H and 25.4% N by mass and has a molar mass of 220 g/mol.

Q9. Oxygen gas can be produced by the decomposition of KClO₃

2KClO₃ (s) ? 2 KCl + 3 O₂ (g)

How many grams of O₂ can be produced from 1.625 g of KClO₃?

Q10. Consider the following balanced reaction: 2 Fe (s) + Al₂O₃ (s) Â® 2 Al (s) + Fe₂O₃ (s)

If 6.25 moles of Fe react with 2.50 moles of Al₂O₃

Which reactant is the limiting reagent?

How many grams of Al are produced?

Q11. Consider the reaction for the manufacture of Aluminum sulfate:

2 AlCl₃ (aq) + 3 H₂SO₄ (aq) ? Al₂(SO₄)₃(aq) + 6 HCl (aq)

If 15.0 g of AlCl₃was mixed with 25.0 g of H₂SO₄, which reactant is the limiting reagent?

Calculate the theoretical yield of Al₂(SO₄)₃.

If only 18.63 g of Al₂(SO₄)₃ was produced, what is the percent yield of Al₂(SO₄)₃?

Q13. How many grams of Nickel (II) chloride are needed to prepare 100.0 ml of 0.125 M solution?

Q14. What volume of 0.125 M KMnO₄ (aq) solution can be prepared from 12.623 g of KMnO₄?

Practice problems for exam 2 ______________

Useful Information:

h=6.626Ã10-34JÂ·s.; c=3.0Ã108 m/sec; E=hï® ; E= hc , ï¬ = h/mv; 1J = 1 kg-m2/s2 ï¬

mass of electron = 9.11 Ã 10-28 g, ïE= q + w ; 1 cal = 4.184 Joules Please Show all Work

1. Which of the following substances have standard heats of formation that are equal to zero by definition (circle your answers): H2(g), H(g), O3(g), H2O(s), H2O(l), Hg(l), Hg(s), Hg(g).

2. Limestone stalactites are formed in the reaction: Ca2+(aq) + HCO3-(aq) ï CaCO3(s) + CO2(g) +

H2O(l)
If one mole of CaCO3 is produced at 298 K under one atmosphere of pressure, the reaction performs 590 calories of expansion work, pushing back the atmosphere as CO2 is formed. At the same time, 9310 calories of heat are absorbed from the environment. What is ïE in Kcal/mole for CaCO3.

3. What is the minimum wavelength of light in AÌ (1 AÌ = 10-8 cm) needed to provide enough energy per quantum to rupture the chemical bond in hydrogen iodide (HI). The bond dissociation energy of HI is 71.4 Kcal/mole.

4. Sketch the shape and orientation of the following types of orbitals: s, px, dxy, dz2, dx2-y2

5. Give the values of (n) , (l) and (ml) for each orbital in the 4p subshell.

6. Write the complete electron configuration for the following: Ti 2+_____________________________________ Cr_______________________________________

N______________________________________

7. Calculate the standard enthalpy of formation ( ï Ho) for diamond from graphite [i.e. C (graphite) ï C (diamond)] given that:

C (graphite) + O2 ï CO2 (g) ( ï Ho = -393.5 KJ/mole) C (diamond)] + O2 ï CO2 (g) ( ï Ho = -395.4 KJ/mole)

If 1.0g of graphite is converted to diamond, what is the energy change? Is this an endothermic or exothermic reaction?

8. An 160 pound astronaut on his way to Mars is buzzing along at 10,000 miles per hour. (a) Express his weight in grams (one pound = 454 grams) so that you can calculate the astronautâs wavelength (1mile/hour = 44.7 cm/sec)

(b) Suppose the astronaut detects outside his spacecraft a proton (m=1.7 x 10-24 g) from a âsolar windâ moving at exactly the spacecraft velocity. What is the proton wavelength is in AÌ (1 AÌ = 10-8 cm.

9. What is the maximum number of electrons that can occupy each of the following subshells? a) 3d_________________ b) 1s____________________ c) 2p ____________________

10. Identify the element represented by the following electronic configuration.

a) [Ne] 3s2____________________

b) What is the electron configuration for the first excited state of this atom.______________

11. Determine the number of valence electrons for each element.
(a) Br___________ (b) Na _________ (c) Sn __________

12. 175 g of Fe at 15.0oC is mixed with 225 g of H2O at 95.0oC. What is the final temperature of the mixture? The specific heats of iron= 0.448 J/g oC and water = 4.184 J/g oC). (keep in mind the following: heat gained + heat lost = 0 and q=mass x heat capacity x ïT)

13. (5 pts) Calculate values of ÎHrxn for the following reactions: CS2(g) + 3O2(g) ï® CO2(g) + 2SO2(g)

The heat of formation for the following substances is given in kJ/mol:

CS2 CO2 SO2 117.4 -393.51 -296.83

14. (6 pts) Use the electron configuration of Li and Be and determine which element has the greatest second ionization energy. Defend your answer.

15. Mark beside each of the following processes either âexoâ or âendoâ according to whether you think the process will release heat or absorb heat.

a. Ca(g) ï Ca(g)+2 + 2e-
b. I(g)+1e-ï I(g)-1
c. Ca(g)+2 + S(g)-2 ï CaS(s) d. I2(g)ï 2I(g)

( ) ( ) ( ) ( )

16. (6 pts) In each of the following pairs, which of the two species is larger?
a) O-2 or Na+ b) Ti+4 or Ti+2 c) B or C d) N or N-3

17. Write down the Lewis dot structure for the following (a) N_______________ (b) Ne________________

18. THE BORN HABER CYCLE: I may have a problem on the Born Haber cycle. Please check my lecture notes to see how to set up the process and then calculate the lattice energy from the various thermodynamic quantities such as in the NaCl example below;

ï H ï¯ f NaCl = -411KJ

Na(s) ï® Na(g) ï H =108KJ
1â2 Cl2 ï® Cl(g) ï H = 122KJ Ionization Energy of Na ï H = 496 KJ Electron affinity of Cl ï H = -349KJ

Balance the following Chemical Equations:

____Fe(s) + ____H₂O(g) Â® ____Fe₃O₄(s) + ____H₂(g)

____C₂H₆(g) + ____O₂(g) Â® ____CO₂(g) + ____H₂O(g)

___ C₆H₁₄ (l) + ___ O₂ (g) Â® ___ CO₂ (g) + ___ H₂O (g)

___ C₃H₈O₃ (l) + ___ O₂ (g) Â® ___ CO₂ (g) + ___ H₂O (l)

___ NaN₃ (s) Â® ___ Na (s) + ___ N₂ (g)

__ C₃H₅N₃O₉ Â® __ CO₂ + ___ N₂ + ___ H₂O + ___ O₂

Write and Balance the equations:

Aqueous calcium hydroxide reacts with aqueous sodium carbonate to produce solid calcium carbonate and aqueous sodium hydroxide.

Solid iron reacts with Oxygen gas to form solid Iron (II) oxide

Copper(II) sulfide is oxidized by molecular oxygen to produce gaseous sulfur trioxide and solid copper(II) oxide. The gaseous product then reacts with liquid water to produce liquid hydrogen sulfate as the only product. Write the two equations which represent these reactions.

Indicate what type, or types, of reaction each of the following represents: (precipitation, acid-base, and oxidation-reduction.)

(A) H₂O(g) + C(s) â¶ CO(g) +H₂(g)

(B) 2KClO₃(s) â¶ 2KCl(s) +3O₂(g)

(D) Pb(NO₃)₂(aq) + H₂SO₄(aq) â¶ PbSO₄(s) + 2HNO₃(aq)

4. Silver can be separated from gold because silver dissolves in nitric acid while gold does not. Is the dissolution of silver in nitric acid an acid-base reaction or an oxidation-reduction reaction? Explain your answer.

5. Determine the oxidation states of the elements in the compounds listed. None of the oxygen-containing compounds are peroxides or superoxides.

(A) H₃PO₄

(B) Al(OH)₃

6. Complete and balance the following acid-base equations:

(A) A solution of HClO₄ is added to a solution of LiOH.

(B) Aqueous H₂SO₄ reacts with NaOH.

7. Write the molecular, total ionic, and net ionic equations for the following reactions:

(A) Ca(OH)₂(aq) + HC₂H₃O₂(aq) â¶

(B) H₃PO₄(aq) + CaCl₂(aq) â¶

8. Write the balanced equation, then calculate the number of moles and the mass of Mg required to react with 5.00 g of HCl and produce MgCl₂ and H₂. Ans: 1.67 g Mg

9. H₂ is produced by the reaction of 118.5 mL of a 0.8775-M solution of H₃PO₄ according to the following equation: 2Cr + 2H₃PO₄ â¶ 3H₂ + 2CrPO₄. How many grams of H₂ are produced? Ans: .315 g H₂

10. Automotive air bags inflate when a sample of sodium azide, NaN₃, is very rapidly decomposed.

2NaN₃(s) â¶ 2Na(s) + 3N₂(g)

What mass of sodium azide is required to produce 2.6 ft³ (73.6 L) of nitrogen gas with a density of 1.25 g/L?

Ans: 142 g NaN₃

11. Urea, CO(NH₂)₂, is manufactured on a large scale for use in producing urea-formaldehyde plastics and as a fertilizer. What is the maximum mass of urea that can be manufactured from the CO₂ produced by combustion of 1.00 x 10⁴ grams of CO₂?

CO₂(g) + 2NH₃(g) â¶ CO(NH₂)₂(s) + H₂O(l)

Ans: 1360 g urea

12. What volume o f 0.750 M hydrochloric acid solution can be prepared from the HCl produced by the reaction of 25.0 g of NaCl with excess sulfuric acid? NaCl(s) + H₂SO₄(l) â¶ HCl(g) + NaHSO₄(s)

Ans: .570 L

13. A sample of 0.53 g of carbon dioxide was obtained by heating 1.31 g of calcium carbonate. What is the percent yield for this reaction? CaCO₃(s)â¶CaO(s) + CO₂(s)

Ans: 92.0 %

14. Citric acid, C₆H₈O₇, a component of jams, jellies, and fruity soft drinks, is prepared industrially via fermentation of sucrose by the mold Aspergillus niger. The equation representing this reaction is

C₁₂H₂₂O₁₁ + H₂O +3O₂ â¶2C₆H₈O ₇+ 4H₂O

What mass of citric acid is produced from the reaction of 150. grams of sucrose if the yield is 92.30%?

Ans: 155 g

15. The phosphorus pentoxide used to produce phosphoric acid for cola soft drinks is prepared by burning phosphorus in oxygen.

(A) What is the limiting reactant when 0.200 mol of P₄ and 0.200 mol of O₂ react according to P₄+5O₂ â¶ P₄O₁₀?

(B) Calculate the percent yield if 10.0 g of P₄O₁₀ is isolated from the reaction.

Ans: 88.0 %

16. What is the limiting reactant when 1.50 g of lithium and 1.50 g of nitrogen combine to form lithium nitride, a component of advanced batteries, according to the following unbalanced equation? Li + N₂ â¶ Li₃N

Ans: Li

17. What is the concentration of NaCl in a solution if titration of 15.00 mL of the solution with 0.2503 M AgNO₃ requires 20.22 mL of the AgNO₃ solution to reach the end point?

AgNO₃(aq) + NaCl(aq) â¶ AgCl(s) +NaNO (aq)

Ans: .3374 M

18. In a common medical laboratory determination of the concentration of free chloride ion in blood serum, a serum sample is titrated with a Hg(NO₃)₂ solution.

2Cl^â(aq) + Hg(NO₃)₂(aq) â¶ 2NO₃^â(aq) + HgCl₂(s)

What is the Cl^â concentration in a 0.25-mL sample of normal serum that requires 1.46 mL of .000825 M Hg(NO₃)₂(aq) to reach the end point?

Ans: 0.009636 M

CHEM 24112 Chapter Notes - Chapter 9: Copper(Ii) Sulfate, Orthogonal Group, Salt Metathesis Reaction

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