CHEM 2100 Chapter Notes - Chapter 12: Bromine, Triethylamine, Zinc Chloride

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12 Sep 2017
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Oh group is on carbon 1, so the locant is omitted. Common names for alcohol alcohol is parent name + group attached to it ex. Oh grp attached to benzene: parent name = phenol. Highest priority alcohol (lowest #) alkane alkyne halogen, alkyl branches (prefixes) Identify substituents with location only count iso and cyclo. 1,4-cyclohexanediol means 2 alcohol groups diol should be lowest numb. If #4 priority group is neither on wedge nor dash: double switch. Draw the most stable chair conformation for: (cis)-1-(1-methylethyl)-1,4-cyclohexanediol isopropyl group, most stable at --> equatorial. Draw parent rectangle with triangle pointing down at one end and up at the other. Cis means the two (di)-ol groups are both pointing up. The mo oh grp hydrophil the more sol. The more ch3 grps hydrophob the less sol. 3c or less per oh grp then molecule will be soluble. Hexylresorcinol antibacterial and antifungal agent water soluble nonpolar region helps it pass thru cell membranes.