CHEM 2261 Chapter : Chap11

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15 Mar 2019
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I have an acidic personality because my spouse, carbonyl oxygen, is always hogging all our electrons. The way it works is this: oxygen"s electrons are oxygen"s electrons and my electrons are oxygen"s electrons too!! Ch3 ch2 c h aldehyde: carbonyl group with carbon on one side and hydrogen on other side. Ch3 ch2 c ch2 ch3 ketone: carbonyl group with carbon neighbors on both sides. Functional group priorities aldehyde ketone alcohol amine alkene/alkyne hydrocarbon skeleton substituents. Alkynes: name and number longest chain with highest priority pathway, n-alk(adi, atri, )en-n-(di, tri, ) yn-n-(di, tri, )al/one becomes root name, number and alphabetize everything else as substituents. Ch2: dec, numbered right to left, 3,9-decadien-6-yn-2,8-dione, 5-hydroxy-4-(4-pentenyl)-3,9-decadien-6- yn-2,8-dione. Ch3 ch ch ch c ch2 ch ch: oct, numbered right to left, 5-octenal, 7-hydroxy-2-methyl-4-oxo-5-octenal. Ch3 c ch3 cyclic ketal- both alcohols in same molecule. Base-catalyzed coupling (aldehydes or ketones) known as aldol condensation. I"m just gonna grab this proton and settle down for a nice nap!