Chemistry 1302A/B Chapter Notes - Chapter 2.1: Exothermic Process, Closed System, Heat Capacity

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Thermodynamics
Thermodynamics: study of the energy changes involved in physical and
chemical processes
Physical processes involve heating and cooling of substances, phase
changes and changes in physical parameters such as the volume &
pressure of a gas
Chemical process involve chemical reactions
Thermochemistry: branch of thermodynamics that investigates the heat flow
that occurs during chemical reactions
Systems & Surroundings
Heat flow: transfer of thermal energy in the process being studied
Heat always flows from the warmer object to the cooler object
A system is the part being studied while the surroundings are the remaining
parts that can interact with a system
Open system: can exchange both matter and energy with its surroundings
Closed system: can exchange energy but not matter with its surroundings
Isolated system: exchanges neither energy nor matter with its
surroundings
Heat Capacity
Measure of how many joules are required to change the temperature of a
substance or object by 1 degree
Heat capacity (
𝐶
): used for objects
Units:
𝐽 𝐶
𝑞 = 𝐶 ⋅ Δ𝑇
Specific heat capacity (
𝑐
): heat needed to warm one mass unit of a substance by
one degree
Units:
𝑞 = 𝑚 ⋅ 𝐶 ⋅ Δ𝑇
Endothermic: system absorbs energy from surroundings
Change in energy (𝑞) is positive
Exothermic: system releases energy to surroundings
Change in energy (𝑞) is negative
Thermal Equilibrium
The # of joules lost by the warmer object must equal to the # of joules gained by
the cooler object
−𝑞./01 = 𝑞234567
Thermal equilibrium: both objects reach the same final temperature and the
heat flow stops
Intensive & Extensive Properties
Intensive property: property that does not depend on the size of the system
Temperature, color, hardness, density
Extensive property: property whose value is proportional to the size of the
system
Mass, length, volume, energy, enthalpy, entropy
State Functions
State function: a property whose value depends only on the current state of the
system but not how that state was reached
Volume, pressure, internal energy, enthalpy, speed
Not heat or work
First Law of Thermodynamics
Total energy of a system and surroundings is conserved
Energy can be neither destroyed nor created, only transferred from one
substance to another
Energy may be transferred through 2 methods: heat and work
Internal energy of a system is equal to the heat transferred when the volume
does not change
Heat and work are equivalent ways are transferring energy in and out of a
system
Δ𝐸 = 𝑞 + 𝑤
Positive + Negative -
𝑞Supply heat to the system
(absorb)
Supply heat to surroundings
(release)
𝑤Surroundings do work on
the system
System does work on
surroundings
2.1 Heat, Work, and Energy
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Document Summary

Thermodynamics: study of the energy changes involved in physical and chemical processes. Physical processes involve heating and cooling of substances, phase changes and changes in physical parameters such as the volume & pressure of a gas. Thermochemistry: branch of thermodynamics that investigates the heat flow that occurs during chemical reactions. Heat flow: transfer of thermal energy in the process being studied. Heat always flows from the warmer object to the cooler object. A system is the part being studied while the surroundings are the remaining parts that can interact with a system. Open system: can exchange both matter and energy with its surroundings. Closed system: can exchange energy but not matter with its surroundings. Isolated system: exchanges neither energy nor matter with its surroundings. Measure of how many joules are required to change the temperature of a substance or object by 1 degree. Specific heat capacity (): heat needed to warm one mass unit of a substance by one degree.

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