BIOL 112 Chapter Notes - Chapter 6: Reaction Rate, Activation Energy, Common Source

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29 Nov 2016

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BIOL 112 Full Course Notes

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Rate of chemical reaction the amount of product formed (or reactant consumed) per unit of time. Play a critical role in determining which chemical reactions take place from all the possible reactions that could occur in a cell central role in metabolism. Transition state highest free energy activation energy (ea) the energy input necessary to reach the transition state. The rate of a reaction is inversely correlated to the height of the energy barrier. Common source of energy used to overcome the energy barrier. Enzymes (in living organisms) reduce the activation energy by stabilizing the transition state and decreasing its free energy. As the activation energy decreases, the speed of the reaction increases. The differe(cid:374)(cid:272)e i(cid:374) free e(cid:374)ergy (cid:271)et(cid:449)ee(cid:374) rea(cid:272)ta(cid:374)ts a(cid:374)d produ(cid:272)ts (cid:894) g(cid:895) does not change. Enzyme changes the path of the reaction, but not the starting or end point. G; reaction rate; types of product generated; activation energy; the laws of thermodynamics.

Related Questions

Question 1 When energy changes from one form to another, some of the energy that can be used to do work is always lost. The loss of this energy is mostly in the form of _________.
a. heat
b. potential energy
c. kinetic energy
d. light energy
e. mechanical energy

Question 2 Which of the following is exergonic?
a. binding fatty acids and glycerol molecules together to form lipids
b. building proteins from amino acids
c. binding sugars molecules together to form glycogen
d. breaking bonds in starch to release glucose
e. adding a phosphate group to ADP to form ATP

Question 3 The first law of thermodynamics states that:
a. energy can neither be created nor destroyed.
b. the universe is increasing in entropy.
c. all living organisms must eat to derive energy.
d. energy is required to bring molecules into a cell against a concentration gradient.
e. in energy-yielding reactions, matter goes from a more-ordered to a less-ordered state.

Question 4 Which of the following is true of energy?
a. It can be transferred from one form to another with 100 percent efficiency.
b. It can be created.
c. It can be stored in chemical bonds.
d. It can never be stored.
e. It can be released by forming chemical bonds.

Question 5 Metabolism is:
a. the sum of all the energy a cell uses.
b. the sum of all the vitamins a cell contains.
c. the sum of all the enzymes a cell contains.
d. the sum of all the chemical reactions that an organism carries out.
e. the sum of all the ATP a cell contains.

Question 6 Entropy is the measure of ________ in a system.
a. disorder
b. order
c. energy
d. work
e. heat

Question 7 What percentage of the energy stored in glucose are humans cells able to use to do useful work?
a. 37%
b. 100%
c. 15%
d. 52%
e. 48%

Question 8 What is activation energy?
a. the energy gained by living things, allowing them to remain active
b. the energy produced by the breakdown of ATP to ADP.
c. the energy required to initiate or begin a chemical reaction
d. the energy created by enzymes during exergonic reactions
e. the energy lost by living things in the form of heat

Question 9 Which of the following is true of allosteric enzymes?
a. Their activity can be reduced when the product binds the enzyme.
b. Their activity can be reduced when a coenzyme binds to them.
c. Their activity can be reduced when the substrate binds the enzyme.
d. Their activity can be increased when the product binds the enzyme.

Question 10 Which of the following is a true statement about enzymes?
a. They are made of proteins.
b. They are altered by the reactions they catalyze.
c. They increase the energy of activation of chemical reactions.
d. All of the above are true.
e. None of the above is true.

Question 11 What is the energy currency of cells?
a. ADP
b. enzymes
c. glucose
d. vitamins
e. ATP

Question 12 Kinetic energy is ____________, while potential energy is _____________.
a. stored energy; energy that is being used
b. stored energy; energy that can't be used
c. energy that is being used; stored energy
d. energy that can't be used; stored energy

Question 13 The energy released during ________ reactions can be used to drive ________ reactions, and this is called ________ reactions.
a. exergonic; endergonic; coupled
b. endergonic; exergonic; coupled
c. exergonic; endergonic; mutually dependent
d. coupled; mutually dependent; independent
e. endergonic; exergonic; mutually dependent

Question 14 ADP + P + Energy --> ATP Which of the following is a true statement about the chemical reaction above?
a. This is a coupled reaction.
b. This is an exergonic reaction.
c. The product of the reaction contains more energy than that of all of the reactants combined.
d. This is an endergonic reaction.
e. This is an example of a catabolic reaction.

greychimpanzee211

Oxidation reduction reactions are coupled and referred to as redox reactions. Electrons are the atomic particles that participate in chemical bonds and are used by cells to generate an electrochemical gradient across membranes. Cells have require ATP to maintain membrane properties and metabolism, because ATP has high energy phosphate bonds that may be cleaved to release energy. Cells synthesize ATP through phosphorylation. Cells must perform many chemical reactions within a certain temperature, pH and osmolarity range. In general chemical reactions in a cell would occur over time without enzymes, and it might require big changes in temperature. Enzymes are organic catalysts that increase the rate of reactions without being altered in the process. Review protein structure and function in chapter 2 to understand how enzymes work. Enzymes also may act as 'switches' and be the rate controlling steps in a biochemcial pathway. There are several ways enzyme activity is altered by other factors or physical conditions.

1. The bacterial enzyme streptokinase is used to digest fibrin in patients with atherosclerosis. Why doesn't the injection of streptokinase cause a streptococcal infection?

2. How do we know that streptokinase will break down fibrin and not functional tissue?

3. 5 bromouracil is used as an anti cancer drug it is mistaken for thymine by cellular enzymes during DNA replication, name the enzyme site the nucleoside analog is probably binding.

Most of a cell's energy is derived from the oxidation of carbohydrates. Glucose is the most common oxidized carbohydrate. There are two types of glucose catabolism respiration and fermentation.

4. Is glucose completely broken down in respiration or fermentation?

greenhedgehog909

Question 1

Plasma membranes are selectively permeable. This means that

	A.	glucose cannot enter the cell.
	B.	the plasma membrane allows some substances to enter or leave a cell more easily than others.
	C.	plasma membranes must be very thick.

Question 2

Oxygen molecules O₂ crosse a plasma membrane by

	A.	passive transport
	B.	osmosis
	C.	active transport

Question 3

Facilitated diffusion across a biological membrane requires ________ and moves a substance ________ its concentration gradient.

		A. energy and channel proteins; against (up)
		B. transport proteins that make channels ; down
		C. energy ; down

Question 4

When two aqueous solutions that differ in solute concentration are placed on either side of a semipermeable membrane and osmosis is allowed to take place, the water will

		A. move to the side with lower water concentration
	B.	move to the side with higher water concentration
	C.	move to the side with lower solute concentration

Question 5

Kinetic energy differs from chemical energy in that

	A.	chemical energy is a particular form of kinetic energy.
	B.	kinetic energy is the energy of a moving object, whereas chemical energy is the potential energy of molecules.
	C.	kinetic energy is stored energy that has the potential to do work, and chemical energy is the energy of movement.

Question 6

When a cell uses chemical energy to perform work, it uses the energy released from a(n) ________ reaction to drive a(n) ________ reaction.

	A.	exergonic; endergonic
	B.	endergonic; exergonic
	C.	spontaneous; exergonic

Question 7

When an enzyme catalyzes a reaction

		A. it raises the activation energy of the reaction.
		B. it lowers the activation energy of the reaction.
		C. it is used once and discarded.

Question 8

Which of the following statements regarding enzyme function is false?

		A. An enzyme's function depends on its three-dimensional shape.
		B. Enzymes are very specific for their substrates.
		C. Enzymes are used up when they catalyze a chemical reaction so must be synthesized for each new chemical reaction

BIOL 112 Chapter Notes - Chapter 6: Reaction Rate, Activation Energy, Common Source

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