CHEM266 Chapter Notes - Chapter 2: Parent Structure, Locant, Substituent

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Hydrocarbons: organic compounds made up of carbon (c) and hydrogen (h) atoms. Divided into 2 groups aliphatic hydrocarbons and aromatic hydrocarbons. All carbon atoms are connected by bonds, lacking bonds. Alkane name methane ethane propane butane pentane hexane heptane octane nonane decane. Parent undec dodec tridec tetradec pentadec eicos triacont tetracont pentacont hect. Alkane name undecane dodecane tridecane tetradecane pentadecane eicosane triacontane tetracontane pentacontane. C directly attached to the parent chain is assigned the number 1 and the longest chain of the substituent is number sequentially. With branched alkyl groups, the name is placed inside a parenthesis. There are systematic and common names for some branched alkyl groups that contain common names. To name branched alkanes, these five steps must be followed: Identify the parent chain (longest continuous uninterrupted chain of carbons in the molecule, may be bent or not) Identify the substituents (groups that are directly connected to the parent chain)

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