FRSC 1011H Chapter Notes - Chapter 14: Forensic Science, Pyrolysis, Spectrophotometry

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Trace Evidence Paint, Glass and Soil
Forensic Examination of Paint
Paint spread onto a surface dries into a hard film that is best described as
consisting of pigments and additives suspended in a binder.
Questioned and known paint specimens are best compared side by side under a
stereoscopic microscope for color, surface texture, and color layer sequence.
Pyrolysis gas chromatography and infrared spectrophotometry are used to
distinguish most paint binder formulations.
Paint Data Query (PDQ) is a computerized database that allows an analyst to
obtain information on paints related to automobile make, model, and year.
Forensic Analysis of Glass
To compare glass fragments, a forensic scientist evaluates density and refractive
index.
The “immersion method” is used to determine a glass fragment’s refractive index.
It involves immersing a glass particle in a liquid medium whose refractive index is
adjusted by varying its temperature. At the refractive index match point, the
visual contrast between the glass and liquid is at a minimum.
The “flotation method” is used to determine a glass fragment’s density. It involves
immersing a glass particle in a liquid whose density is carefully adjusted by
adding small amounts of an appropriate liquid until the glass chips suspends in
the liquid medium.
By analyzing the radial and concentric fracture patterns in glass, the forensic
scientist can determine the side of impact by applying the 3R’S rule: Radial
cracks form a Right angle on the Reverse side of the force.
Forensic Analysis of Soil
A side by side visual comparison of the color and texture of soil specimens
provides a way to distinguish soils that originated from different locations.
Minerals are naturally occurring crystalline solids found in soil. Their physical
properties-for example, their color, geometric shape, density, and refractive
index-are useful for characterizing soils
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Document Summary

Paint spread onto a surface dries into a hard film that is best described as consisting of pigments and additives suspended in a binder. Questioned and known paint specimens are best compared side by side under a stereoscopic microscope for color, surface texture, and color layer sequence. Pyrolysis gas chromatography and infrared spectrophotometry are used to distinguish most paint binder formulations. Paint data query (pdq) is a computerized database that allows an analyst to obtain information on paints related to automobile make, model, and year. To compare glass fragments, a forensic scientist evaluates density and refractive index. The immersion method is used to determine a glass fragment"s refractive index. It involves immersing a glass particle in a liquid medium whose refractive index is adjusted by varying its temperature. At the refractive index match point, the visual contrast between the glass and liquid is at a minimum. The flotation method is used to determine a glass fragment"s density.

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