CHEM 1002 Chapter 11: Organic Reactions
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15 Aug 2015
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Show electron movement in a reaction using curved arrows. All chemical reactions happen as a result of the movement of electrons. Substitution as well as elimination and addition reactions involved the attraction of an electrophile to a nucleophile. Predict products from sn2 and sn1 reactions. Explain mechanisms of sn2 and sn1 reactions. Recognize nucleophile, substrate, product, and leaving group in nucleophilic substitution reaction. State factors that make good nucleophile and good leaving group. Draw the flow of electrons in substitution reactions using curved arrows. Predict stereochemistry of product of substitution reaction involving chiral substrate. Predict effects of different substrates on rates of substitution reactions. Predict whether sn1 or sn2 reaction will occur for reaction. Sn1 reactions occur via formation of carbocation followed by its reaction with nucleophile. Rates of substitution reactions are sensitive to type of substrate, nucleophile, and leaving group. The sn2 mechanism substitution reactions that have both steps occur simultaneously: s stands for substitution, n stands for nucleophilic.
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