CHE 321 Midterm: E3_Mega_Review_Sheets

• School: Stony Brook University
• Department: Chemistry
• Course: CHE 321
• Professor: grubbs

Document Summary

Todd"s chapter 8 review sheet: hydrogen halide. Both (anti, syn: acid catalyzed hydration a. If no h 2o then this is product if h 2o then same as above: halogenation. Z = en atom with a lone pair (ie: br, or, oh, sh) Z = en atom without a lone pair (ie: c=o , no2, z+) C h 3: oxidative cleavage rules, alkenes. Kmno4 /warm or o3 with zn or (ch3)2s. If you create a chiral center then 50:50 (r & s) For every bh 3 you make 3 alcohols. If you did not create chiral center then it remains the same configuration. H 2 or d 2 or t 2. Trans -> anti -> meso d + d. Allyl > 3o > 2o > 1o > me. Intramolecular reactions best when you can make a 5 or 6 member ring. Chapter 9 (nmr) y g r e n.