CHEM 2312 Midterm: CHEM 2312 GT Examp5ii

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15 Feb 2019
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E4 practice ii: (32 points) circle the letter on the right which corresponds to the answer to each question. Oh (vii) which of the following does not have the compounds in order of decreasing acid strength (more acidic > less acidic): ch3cooh > ch3ch2oh > ch3ch3. Oh: (38 points) (a) provide the structure of the major organic product obtained from each of the following reactions. Nh(ch3)2 (b) (i) explain (one sentence and a structure) why the pka of propanamide, ch3ch2conh2, is lower than the pka of propylamine, ch3ch2ch2nh2 (ii) draw the isocyanate intermediate in the hofmann rearrangement of propanamide, ch3ch2conh2 (reaction with. Br2, naoh, h2o: (30 points) the following transformations cannot be completed in a single step. Provide a sequence of reactions to perform each transformation, showing the reagents and structures of all isolated synthetic intermediates. The synthesis must use the given starting materials; you may also use any other starting materials with 3 or fewer carbon atoms.

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