CHEM 250 Study Guide - Final Guide: Valence Bond Theory, Acyl Halide, Grignard Reaction
Document Summary
Hybridization of nitrogen, oxygen, phosphorus and sulfur. Chapter 2 polar covalent bonds; acids and bases. Acids and bases: bronsted-lowry, acid base strength, pka, organic acids and bases, lewis acids and bases. Evidence for mechanism of electrophilic additions: carbocation arrangements. Alkyllation and acylation of aromatic rings: friedel-crafts. Substiteuent effects in electrophilic substitution: activating and deactivating effects, orienting effects: ortho and para, meta. Oxidation and reduction of aroatic compounds: oxidation of alkylbenzenes, hydrogenation of aromatic rings, reduction of aryl alkyl ketons. Oxidation of alkenes: cleavage to carbonyl compounds. Addition of carbenes o alkenes: cyclopropane synthesis. Radical additions to alkenes: chain growth polymers. Preparing alkyl halides from alkenes: allylic bromination. Sn1: solvent, substrate, nucleophile, leaving group, solvent. Chapter 13 alcohols, phenols, and thiols; ethers and sulfides. Reactions of alcohols: reduction of carbonyl compounds, grignard reactions of carbonyl compounds, dehydration of alcohols, conversion of alcohosl into esters, oxidation of alcohols, oxidation of phenols: quinones.
