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18 Dec 2019

Temp %A in Vapor %A in Liquid
70 100 100
75 97 79
80 93 65
85 85 55
90 77 45
95 69 37
100 60 28
105 50 20
110 40 12
115 25 6
120 0 0

The table above shows the % compositions of the vapor and liquid phases at equilibrium for solutions of A and B at the indicated temperatures:

1). A mixture of 30g of A and 70g of B is distilled using a dimple distillation apparatus. At what temperature would the first drop distill?

2). A misture of 50g of A and 50g of B is distilled usinga very efficient fractionating column. Construct a distillation curve (temperature vs. mL of distillate) for this system knowing that the density of A and B is 1.05g/mL and 0.96g/mL, respectively.

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