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18 Dec 2019

Table #1: Volumes

Trial

Deionized Water (mL)

1.0 M KI (mL)

H2O2 (mL)

Temperature of Tap Water (◦C)

1

100

50

50

18.7

2

125

25

50

19.3

3

125

50

50

19.5

4

100

50

50

50.0

Table #2: Trial #1 data

Time (min)

Volume (mL)

Time (min)

Volume (mL)

3

0

8

12

4

1

9

15

5

4

10

18

6

6

11

25

7

8

12

27

Table #3: Trial #2 data

Time (min)

Volume (mL)

Time (min)

Volume (mL)

6.27

0

11.27

6

7.27

1

12.27

7

8.27

3

13.27

9

9.27

4

14.27

11

10.27

6

15.27

12

Table #4: Trial #3 data

Time (min)

Volume (mL)

Time (min)

Volume (mL)

5.37

0

9.37

5

6.37

2

10.37

6

7.37

3

11.37

8

8.37

4

12.37

9

Table #5: Trial #4 data

Time (min)

Volume (mL)

Time (min)

Volume (mL)

1.30

0

6.30

62

2.30

5

7.30

82

3.30

13

8.30

100

4.30

26

9.30

115

5.30

41

10.30

132

Table #6: Results

Trial

Temperature (K)

3% H2O2 (M)

KI (M)

Rate (L/min)

1

291.85

0.176

0.005

0.00225

2

292.45

0.176

0.0025

0.00075

3

292.65

0.176

0.005

0.0009

4

323.15

0.176

0.005

0.0132

Above are 6 tables of data from an experiment I performed. My goal is to determine the reaction order with respect to H2O2 and I- , the rate law for the reaction, and the activation energy for the reaction. My first issue is table #6. I do not believe that I have figured the correct (M) for the H2O2 and KI or the correct rate. I am supposed to make sure to express the concentrations based on the values after dilution due to mixing. I am not sure how to correctly calculate that.

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