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18 Dec 2019

Calculate the pH of a solution containing a salt AcNa derived from a strong base (NaOH) and a weak acid (AcH), like CH3COONa, KF, NaNO2 and so on. In this case two processes have to be considered:

1. Dissociation of the salt, within the assumption that the salt is a strong electrolyte:

AcNa → Ac- + Na+, for instance: CH3COONa → CH3COO- + Na+

2. the hydrolysis of the water

Ac- + H2O ⇌ AcH + OH-, for example: CH3COO- + H2O ⇌ CH3COOH + OH-

knowing that the initial concentration of the salt is 0.17 M and the acid dissociation constant, Ka , is 1.08e-7.

pH=?

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Jamar Ferry
Jamar FerryLv2
31 Dec 2019

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