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13 Dec 2019

4-draw not write the products of the effect of the leaving group on an Sn2 reactions

a. 1-bromobutane with NaI in acetone

b. 1-chlorobutane with NaI in acetone

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Related questions

I'm confused on how exactly I can explain the reactivities ofSN2 (NaI in acetone) and SN1 (AgNO3 in ethanol) reactions withalkyl halides such as 2-chlorobutane, 2-bromobutane, crotylchloride, etc. Do I explain how the leaving group leaves and thenucleophile attacks the carbon? What is an example explanation andwhat do I include in the explanation?

A. Arrange the organic halides below in order of decreasing experimental reactivity toward iodide ion (NaI in acetone).

B. Are there significant differences in the bromides and chlorides?

C. What structural change correlates with reactivity in this mechanism (it should be SN2, right?)?

Please explain answers! Thank you!

halide reagents:

1-bromobutane, 2-bromobutane, 1-chlorobutane, 2-chlorobutane, benzyl chloride, 2-bromo-2-methylpropane, chlorobenzene, bromobenzene, 2-chloro-2-methylpropane

Write equations for the reactions investigated. Label Sn1 or Sn2.

1)Butyl bromide in 15%NaI-acetone

2)Butyl bromide in 1%ethanolic silver nitrate

?????3)Butyl chloride in 15% NaI-acetone

4) Butyl chloride in 1% ethanolic silver nitrate

5)Sec-butyl chloride in 15%NaI-acetone

6) Sec-butyl chloride in 1% ethanolic silver nitrate

7) Tert-butyl chloride in 15%NaI-acetone

8) Tert-butyl chloride in 1% ethanolic silver nitrate

9) Crotyl chloride in 15% NaI-acetone

10) Crotyl chloride in 1% ethanolic silver nitrate

Any help would be appreciated! I will rate your response in return!

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