A pure substance with a molar mass of 0.122 kg/mol has solid and liquid phases with
densities of 1.08Ã ~103 kg/m3 and 1.01Ã ~103 kg/m3, respectively, at its standard melting point of
427. K. The standard boiling point for this pure substance is 550. K, with a molar enthalpy
of vaporization of 2.20Ã ~104 J/mol.
a. The melting point for this pure substance increases to 429. K if the pressure is increased
to 1.20Ã ~107 Pa. Determine Î fusSm (in J/mol-K) for the substance, assuming both Î fusSm & Î fusVm are independent of temperature and pressure.
b. Determine the boiling point (in K) for this pure substance when the pressure is 2.00 bar.
c. The standard boiling point rises by 2.00 K when 2.00 mol of naphthalene is dissolved in 10.0 kg of the substance. Determine whether naphthalene experiences net dissociation, net association, or neither in this solvent based on the apparent vanât Hoff factor for naphthalene in this substance, assuming the solution is sufficiently dilute.
A pure substance with a molar mass of 0.122 kg/mol has solid and liquid phases with
densities of 1.08Ã ~103 kg/m3 and 1.01Ã ~103 kg/m3, respectively, at its standard melting point of
427. K. The standard boiling point for this pure substance is 550. K, with a molar enthalpy
of vaporization of 2.20Ã ~104 J/mol.
a. The melting point for this pure substance increases to 429. K if the pressure is increased
to 1.20Ã ~107 Pa. Determine Î fusSm (in J/mol-K) for the substance, assuming both Î fusSm & Î fusVm are independent of temperature and pressure.
b. Determine the boiling point (in K) for this pure substance when the pressure is 2.00 bar.
c. The standard boiling point rises by 2.00 K when 2.00 mol of naphthalene is dissolved in 10.0 kg of the substance. Determine whether naphthalene experiences net dissociation, net association, or neither in this solvent based on the apparent vanât Hoff factor for naphthalene in this substance, assuming the solution is sufficiently dilute.