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11 Dec 2019

coffee cup calorimeter contained 50.0 mL of a 1.33 M KOH solution at an initial temperature of 23.3 ºC. A student quickly add 40.0 mL of 1.54 M HNO3 to the calorimeter. The maximum temperature reached during the neutralization reaction was 29.1ºC.

assume specific heat of solution is the same as specific heat of water = 4.18 J/gºC

assume density of both KOH and HNO3 are the same as water = 1.00 g/mL

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This is more of a question regarding the question itself.

What's the difference in finding the mass using Mass = moles*Molar mass = (Molarity×Volume)*Molar mass

and finding mass using Mass = Density*Volume

There is obviously a big difference in these values.

For example, finding the mass of KOH using molarity and volume

Mass = (1.33)*(50*10^-3)*56.105 = 3.73g

Using density it'll be Mass = 50* 1 = 50g

What's the difference, and which method is the most correct?

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Deanna Hettinger
Deanna HettingerLv2
13 Dec 2019

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