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18 Nov 2019

Physical Chemistry II

1. Consider a 1.00 m3 tank containing pure N2 at 20.0°C and 5.00 bar. Assume the N2 molecules are rigid spheres with a diameter of 0.37 nm.

a) What is the mean free path of the N2 molecules in the tank?

b) What is the mean free path of N2 molecules at 20.0°C and 1.0 x 1036 torr (a typical pressure in a vacuum system)?

2. What is the pressure at the top of a 75.0 meter high cylinder containing CO2 at 25.0°C if the pressure at the bottom of the cylinder is 10.00 bar?

3. The thermal conductivity of CH4 gas at 25°C and 1 atm is 3.4 x 1034 J cm31 K31 s31. Estimate the heat per square centimeter that would flow in 10 minutes between two reservoirs as in figure 15.1 connected by a 25 cm long cylinder containing CH4 gas at 1.0 atm. Assume steady state conditions with T2=28°C and T1=24°C.

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Reid Wolff
Reid WolffLv2
10 Jan 2019

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