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17 Nov 2019

The triple point of water is at 273.16 K and 611.73Pa. Near the triple point, the enthalpy of vaporization of
H2O is 44.07 kJ/mol and the enthalpy of fusion is 6.008 kJ/mol (assume both are constant at all temperatures).The density of the solid ice is 0.917 g cm-3 and the density of the liquid is 0.9998 g cm-3 near the triple point.Assume the vapor behaves ideally.

Make a quantitative graph of the phase diagram of water (P vs T phase boundaries) in the vicinity of the triplepoint Do not make any approximations that the curves are linear for the liquid/gas or solid/gas boundaries Hint:to plot the near-vertical liquid/solid line on this scale, you will need to pick a very narrow range of temperaturesin your spreadsheet or graphing program. A range of -10 Celsius to +10 Celsius and 0 to 1600 Pa is suggested

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Sixta Kovacek
Sixta KovacekLv2
30 Oct 2019

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