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11 Nov 2019

The structure of 2,3-dimethylbutane is shown in the figure. Draw a graph of approximate energy vs. the H–C–C–H dihedral angle for this compound as it rotates along the central C–C bond. The first column should show the energy of the conformer with an H–C–C–H dihedral angle of 0°, the second with a dihedral angle of 60°, etc. I have provided a table of energies of different interactions for your convenience.

Interaction Cost in kcal/mol
CH3–CH3 anti 0.0
CH3–CH3 gauche 0.9
H–H eclipse 0.9
CH3–H eclipse 1.7
CH3–CH3 eclipse 4.4

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Casey Durgan
Casey DurganLv2
17 Jul 2019

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