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11 Nov 2019

1. An experimental melting point is always reported as a range of temperatures (for example 171-174˚C). A student observed the following while taking a melting point: “The sample started shrinking at 93˚C. At 95˚C some liquid appeared. By 97˚C, the sample was a pool of liquid with a chunk of solid suspended in it. The suspended solid continued turning into liquid, becoming completely liquid at 98˚C”.

a)What should the student report as the melting point?

b) What two types of information about an unknown solid can be obtained from its experimental melting point?

c) Suppose that a pure unknown compound could be either compound A, compound B, or neither. The following information was obtained: The listed reference melting points are: compound A is 111-112˚C, compound B is 145-147˚C. The experimental melting for the unknown alone was 145-147˚C. The experimental melting point of a mixture of the pure unknown with pure B was 135-146˚C The compound is therefore: (pick one): Compound A, Compound B, neither A nor B. Explain.

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Nelly Stracke
Nelly StrackeLv2
10 Jan 2019

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