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10 Nov 2019

You wish to measure the concentration of methyl benzoate in aplant stream by gas chromatography. You prepare a sample of butylbenzoate to use as an internal standard. A preliminary run, shownat the right involved a solution containing 1.31 mg/mL of methylbenzoate (peak A) and 1.44 mg/mL of butyl benzoate (peak B). Thearea of peak A was determined to be 345 and of peak B to be 403(measured in arbitrary units by the computer). To measure thesample, 1.00 mL of a standard sample of butyl benzoate containing2.73 mg/mL was mixed with 1.00 mL of the plant stream material, andanalysis of the mixture gave a peak area of 471 for peak A and 393for peak B. What is the concentration of the methyl benzoate in theplant stream?

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