University College - Chemistry Chem 112A Lecture Notes - Lecture 28: Lead, Rechargeable Battery, Alkaline Battery

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30 march 2016: can solve for ph using the nernst equation (solve for q, can get [h3o+] and then ph) Lecture 28: equilibria and cells: ex: zn(s)|zn2+ || h3o+|h2|pt(s, using g to relate equilibria and electrochemistry, relating equilibria and electrochemistry. Practical cells: primary cell: limited fuel, non-rechargeable, ie- leclanche cell, acid flashlight battery, zn anode casing: zn(s) zn2, inert graphite electrode, nh4. + nh4: mno2 cathode: mno2(s, overall: zn(s) + mno2(s) + nh4, alkaline battery uses koh as an electrolyte. +/cl- act as salt bridge (aq) + 2e- , (cid:3042)0 = 0. 76 v. + + 2e- mn2o3(s) + 2nh3(aq) + h2o(l), (cid:3032)(cid:3031)0 = 0. 75.

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