CM-UY 1004 Lecture Notes - Lecture 5: Fluorine, Ionic Radius, Atomic Radius

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25 Aug 2016
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Sizes of atoms and ions, nonbonding atomic radius or the van der waals radius a. i. The shortest distance separating the two nuclei during collisions is twice the radii of the atoms: bonding radius b. i. Based on the distance separating the nuclei when the two atoms are bonded to each other b. ii. Shorter than the nonbonding atomic radius: periodic trends in atomic radii c. i. Within each group, bonding radius tends to increase from top to bottom c. i. 1. Outer electrons have a greater chance of being farther away from the nucleus c. ii. Within each period, bonding atomic radius tends to decrease from left to right c. ii. 1. Increase in effective nuclear charge which draws the valence electrons to move closer to the nucleus c. iii. Cations are smaller than their parent atoms c. iii. 1. a. Electrons are removed from the occupied atomic orbitals that are the most spatially extended from the nucleus c. iii. 1. b. Anions are said to be larger than their parent ions c. iii. 2. a.

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