CHEM 1101 Lecture Notes - Stereoisomerism

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5: stereoisomers molecules with the same connectivity, but the same bonds are oriented differently atoms in different positions (orientation different), stereoisomerism due to restricted rotation about is called cis trans isomerism, a cis isomer (or z isomer) has two like groups on the same side of a line drawn through a double bond (chain moves from up to down then moves up again), a trans isomer (or e isomer) has two like groups on opposite sides of a line drawn through a double bond (chain moves from down to up), homologous series: related compounds that differ by the number of subgroups, methylene group ( ch2 ) Methyl group ( ch3) per molecule: naming alkanes, naming alkenes and alkynes, the suffix ene is used when double bonds are present or yne when triple bonds are present, when a chain has 4 or more carbon atoms, the chain is numbered for the position of the multiple bond.

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