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CHMA11H3 Lecture Notes - Lecture 1: Linear Combination Of Atomic Orbitals, Trigonal Planar Molecular Geometry, Bipyramid

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12 Jan 2018

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CHMA11H3 Full Course Notes

CHMA11H3 Full Course Notes

Document Summary

1 mol c3h8: -2044 kj or 5 mol o2: -2044 kj there are 2 mol co2 and 4 mol h2o formed in the reactions. C3h8 (g) + 5 o2 (g) 2 co2 (g) + 4 h2o (g) The magnitude of rh is for the stoichiometric amounts of reactants and products for the reaction as written. A + 2 b c (multiple of reaction) rh 1. 2 a + 4 b 2 c (reverse of reaction) rh 2 = 2 x rh 1. 2 a + 4 b 2 c rh 2 = 2 x rh 1. A + 2 b d h rxn = rh 1 + = rh 4 (sum of reactions) Determining enthalpies of reaction from standard enthalpies of formation. Calculating the standard enthalpy change for a reaction. Standard enthalpy of formation ( rh ) (aka standard heat of formation): for a pure element in its standard state fh = 0. Reactants products rh = rh1 + rh2.

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Related Questions

The oxidation of hydroquinone by hydrogen peroxide in an aqueousenvironment produces quinone and water: C6H4(OH)2(aq) + H2O2(aq)-> C6H4O2(aq) + 2H2O(l) Other related reactions and theircorresponding reaction enthalpies are:

1. C6H4(OH)2(aq) -> C6H4O2(aq) + H2(g)

2. H2(g) + O2(g) -> H2O2(aq)

3. H2(g) + (1/2)O2(g) -> H2O(g)

4. H2O(g) -> H2O(l)

1. ÎH = 177.4 kJ/mol
2. ÎH = -191.2 kJ/mol

3. ÎH = -241.8 kJ/mol

4. ÎH = -43.8 kJ/mol

1. (a) What is the enthalpy change of reaction of the oxidationof hydroquinone by hydrogen peroxide in an aqueous environment, asgiven above? 1. (b) Is the oxidation reaction of hydroquinone byhydrogen peroxide endothermic or exothermic? Briefly justify youranswer in one or two sentences by referring to Îqp of the reaction.-2- 1. (c) What is the standard molar enthalpy of formation ofH2O2(aq)? What is the standard molar enthalpy of formation ofH2O(l)? 1. (d) The enthalpy of an O=O bond is 499 kJ/mol. Using theinformation given, estimate the bond enthalpy of the O-O bond inH2O2(aq). The bonds in H2O2 are: H-O-O-H.

At constant pressure, the combustion of 10.0 g of C2Hg(g) releases 518 kJ of heat. What is AH for the reaction given below? 2 C2H6(g) +- 7 O2(g) rightarrow 4 CO2(g) + 6 H2O(l). -779 kJ -1560 kJ -86.1 kJ -3120 kJ Use the information provided to determine Delta H degree r times n for the following reaction: CH4(g) + 3 Cl2(g) rightarrow CHCI3(I) + 3 HCI(g) Delta H degree r times n = ? -217 kJ -335 kJ +662 kJ +117 kJ -151 kJ Choose the reaction that illustrates Delta H degree f for NaHCO3. Na(s) + 2 H(g) + C(s) + 3 O(g) rightarrow NaHCO3 (s) Na(s) + H2(g) + C(s) + O2(g) rightarrow NaHCO3 (s) Na+(aq) + H2O (I) + CO2 (g) rightarrow NaHCO3 (s) Na(s) + 1/2 H2(g) + C(s) + 3/2 O2(g) rightarrow NaHCO3 (s) Na+(aq) + HCO3 -1 (aq) rightarrow NaHCO3 (s) Use the standard reaction enthalpies given below to determine Delta H degree r times n for the following reaction: 4 SO3(g) rightarrow 4 S(s) + 6 O2(g) Delta H degree r times n = ? Given: SO2(g) rightarrow S(s) + O2(g) Delta H degree r times m = +296.8 kJ 2 SO2(g) + O2(g) rightarow 2 SO3(g) Delta H degree r times n = -197.8 kJ -494.6 kJ -791.4 kJ 1583 kJ -293.0 kJ -692.4 kJ Which of the following statements is TRUE? State functions do not depend on the path taken to arrive at a particular state. Energy is neither created nor destroyed, excluding nuclear reactions. Delta Hr times r can be determined using constant pressure calorimetry. Delta H r times n can be determined using constant volume calorimetry. All of the above are true. How much energy is evolved during the formation of 98.7 g of Fe, according to the reaction below? Fe2O3(s) + 2 Al(s) rightarrow Al2O3(s) + 2 Fe(s) Delta H degree r times n = 852 kJ 01.51 times 103 kJ 241 kJ 0482 kJ 4.20 x 103 kJ 753 kJ Given w = 0, an endothermic reaction has the following. - Delta H and + Delta E Delta H and -Delta E - Delta H and -Delta E + Delta H and +Delta E Which of the following substances (with specific heat capacity provided) would show the greatest temperature change upon absorbing 100.0 J of heat? 10.0 g ethanol, Celharol = 2.42 J/g degree C 10.0 g Ag, CAg = 0.235 J/g degree C 10.0 g Au, CAu = 0.128 J/g degree C 10.0 g Fe, CFe = 0.449 J/g degree C 10.0 g H2O, CHO = 4.18J/g degree C Which of the following processes is endothermic? a hot cup of coffee (system) cools on a countertop the vaporization of rubbing alcohol the chemical reaction in a "hot pack" often used to treat sore muscles the freezing of water the combustion of propane

Show transcribed image text At constant pressure, the combustion of 10.0 g of C2Hg(g) releases 518 kJ of heat. What is AH for the reaction given below? 2 C2H6(g) +- 7 O2(g) rightarrow 4 CO2(g) + 6 H2O(l). -779 kJ -1560 kJ -86.1 kJ -3120 kJ Use the information provided to determine Delta H degree r times n for the following reaction: CH4(g) + 3 Cl2(g) rightarrow CHCI3(I) + 3 HCI(g) Delta H degree r times n = ? -217 kJ -335 kJ +662 kJ +117 kJ -151 kJ Choose the reaction that illustrates Delta H degree f for NaHCO3. Na(s) + 2 H(g) + C(s) + 3 O(g) rightarrow NaHCO3 (s) Na(s) + H2(g) + C(s) + O2(g) rightarrow NaHCO3 (s) Na+(aq) + H2O (I) + CO2 (g) rightarrow NaHCO3 (s) Na(s) + 1/2 H2(g) + C(s) + 3/2 O2(g) rightarrow NaHCO3 (s) Na+(aq) + HCO3 -1 (aq) rightarrow NaHCO3 (s) Use the standard reaction enthalpies given below to determine Delta H degree r times n for the following reaction: 4 SO3(g) rightarrow 4 S(s) + 6 O2(g) Delta H degree r times n = ? Given: SO2(g) rightarrow S(s) + O2(g) Delta H degree r times m = +296.8 kJ 2 SO2(g) + O2(g) rightarow 2 SO3(g) Delta H degree r times n = -197.8 kJ -494.6 kJ -791.4 kJ 1583 kJ -293.0 kJ -692.4 kJ Which of the following statements is TRUE? State functions do not depend on the path taken to arrive at a particular state. Energy is neither created nor destroyed, excluding nuclear reactions. Delta Hr times r can be determined using constant pressure calorimetry. Delta H r times n can be determined using constant volume calorimetry. All of the above are true. How much energy is evolved during the formation of 98.7 g of Fe, according to the reaction below? Fe2O3(s) + 2 Al(s) rightarrow Al2O3(s) + 2 Fe(s) Delta H degree r times n = 852 kJ 01.51 times 103 kJ 241 kJ 0482 kJ 4.20 x 103 kJ 753 kJ Given w = 0, an endothermic reaction has the following. - Delta H and + Delta E Delta H and -Delta E - Delta H and -Delta E + Delta H and +Delta E Which of the following substances (with specific heat capacity provided) would show the greatest temperature change upon absorbing 100.0 J of heat? 10.0 g ethanol, Celharol = 2.42 J/g degree C 10.0 g Ag, CAg = 0.235 J/g degree C 10.0 g Au, CAu = 0.128 J/g degree C 10.0 g Fe, CFe = 0.449 J/g degree C 10.0 g H2O, CHO = 4.18J/g degree C Which of the following processes is endothermic? a hot cup of coffee (system) cools on a countertop the vaporization of rubbing alcohol the chemical reaction in a "hot pack" often used to treat sore muscles the freezing of water the combustion of propane