MBB 222 Lecture Notes - Lecture 4: Reaction Quotient, Dissociation Constant, Molar Concentration
4 Dec 2016
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Document Summary
Eequilibrium constant vs mass-action ratio or reaction quotient. Forward direction of reaction vs reverse direction of reaction. Binding affinity 159-161 and unit 3 affinity package. Dissociation constant vs association constant or binding constant. Molar units equilibrium constant vs activity equilibrium constant. Fraction occupancy unit 3 package affinity also pages 160-161. Fractional saturation or occupancy or occupancy probability. Essentially complete occupancy or predominately complete occupancy. Standard free energy of a reaction unit 3 package affinity pages 507-510. Free energy change, delta g in general usage. Standard free energy of a binding vs standard free energy of a dissociation. Standard free energy change without biochemical convention. Standard transformed equilibrium constant and free energy change. Sum of species vs exact atomic species. Net driving force (actual free energy) for a reaction, deltag-prime. Microscopic reactions affinity package pages 58-59 and 201. Unimolecular vs bimolecular reaction first order vs second order rate constant.
