CHEM 2301 Chapter Notes - Chapter 11: Sigma Bond, Triple Bond, Pi Bond

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Internal alkyne has a c atom bonded to each c atom of the triple bond. Terminal alkyne has the triple bond at the end of the c chain. Formula of cnh2n-2 - 4 fewer h than the maximum number. Triple bond has 2 degrees of unsaturation. Triple bonded c are sp hybridized and linear. 1 sigma bond and 2 pi bonds. Sigma vons is end on overlap of 2 sp hybrid orbitals. Pi bond is side by side overlap by 2 2p orbitals. Both pi bonds are weaker than a sigma bond making them more easily broken and undergo many addition reactions. Are more polarizable than alkenes because electrons are more loosely held. Choose the longest c chain that contain both atoms of the triple bond and number chain to give triple bond the lowest number. Compound with 2 triple bonds are diynes and 3 = triynes. With a double and triple bond = enynes.

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