BSC-2010 Chapter Notes - Chapter 4: Electronegativity, Sulfur, Thiol

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26 Aug 2016
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In larger molecules, the tetrahedral shape of carbon bonded to four other atoms is often a repeating motif. d. Seven functional groups: six are hydrophilic (increase solubility in water) you. Have to know them for exam: 1. Hydroxyl group (-oh): h atom forms a polar covalent bond with o atom, which forms a polar covalent bond to the carbon skeleton a. i. Polar covalent bonds improve solubility of organic molecules: 2. Carbonyl group (>c=o): oxygen atom joined to the carbon skeleton by a double bond. b. i. Ketone: carbonyl group is not on the end b. ii. Aldelhyde: carbonyl group is on the end b. iii. Isomers with aldehydes versus ketones have different properties: 3. Carboxyl group (-cooh): carbon atom with a double bond to an oxygen atom and a single bond to a hydroxyl group c. i. A carboxyl group acts as an acid because of combined electronegativities of two adjacent o atoms: 4.

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