3 Nov 2021
Problem 8
Page 422
Section: Problems by Topic
Chapter 10: Chemical Bonding II: Molecular Shapes, Valence Bond Theory,and Molecular Orbital Theory
Textbook ExpertVerified Tutor
3 Nov 2021
Given information
Here, we are given the species 
and 
and we have to determine which one has smaller bond angle.
Step-by-step explanation
Step 1.
In and chlorine is central metal atom.
Electronic configuration of chlorine is 
that is it has 
valence electron.
Electronic configuration of oxygen is 
that is it has 
valence electron.
Thus in case of since oxygen requires 
electrons and there is one negative charge, chlorine forms double bonds with 
oxygen and one single bond with one oxygen. That is a total of 
bond pairs.
In case of since oxygen requires 
electrons and there is one negative charge, chlorine forms double bonds with oxygen and one single bond with one oxygen. Remaining electron forms one lone pair. That is bond pairs and one lone pair.
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