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13 Dec 2019

Carbonic acid (H2CO3) is a weak diprotic acid with Ka1=4.43�10^-7 and Ka2=4.73�10^-11. When sodium bicarbonate (NaHCO3) is titrated with hydrochloric acid (HCl), it acts as a weak base according to the equation

NaHCO3(aq)+HCl(aq)?H2CO3(aq)+NaCl(aq)

1)What volume of 0.180M HCl is required for the complete neutralization of 1.50g of NaHCO3 (sodium bicarbonate)?

2)What volume of 0.120M HCl is required for the complete neutralization of 1.10g of Na2CO3 (sodium carbonate)?

3)A sample of NaOH (sodium hydroxide) contains a small amount of Na2CO3 (sodium carbonate). For titration to the phenolphthalein endpoint, 0.160g of this sample requires 23.98 mL of 0.100 M HCl. An additional 0.700 mL of 0.100 M HCl is required to reach the methyl orange endpoint. What is the percentage of Na2CO3 by mass in the sample?

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Jarrod Robel
Jarrod RobelLv2
17 Dec 2019
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