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13 Dec 2019

Could someone help me out with these three questions.Thanks.

1) If 3.15kg of sulfur reacts w. oxygen according to theequation below, calculate the volume of SO2 gas (in mL) formed at30.5*C and 1.04 atm.

S(s) + O2(g) --> SO2(g)

2) An aqueous solution of barium hydroxide has a pH of 9.78 at25*C. Calculate the concentration of the base.

3) What is the original molarity of an aqueous solution ofammonia (NH3) whose pH is 11.22 at 25*C? (Kb for NH3 = 1.8 x10^-5).

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(3) When 75.0 mL of a 0.100 M lead (II) nitrate solution is mixed with 100.0 mL of a 0.190 M potassium iodide solution, a yellow-orange precipitate of lead (II) iodide is formed. a. Write the balanced molecular and net-ionic equation. b. Assuming 100% yield calculate the mass of lead (II) iodide formed. c. Determine the molarities of ions left in solution after the reaction.

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(5) How many grams of pure H2SO4 can be obtained from 250 g of iron ore if the ore is 82.0 % (w/w %) FeS2. The reactions involved are given below: 4FeS2 + 11O2 → 2Fe2O3 + 8SO2 (95.0% efficient) 2SO2 + O2 → 2SO3 (90.0 % efficient) SO3 + H2O → H2SO4 (90.0 % efficient)

(6) 30.0 mL of 0.512 M sulfuric acid was added to 25.0 mL of 0.666 M sodium hydroxide. a. Write the balanced chemical equation. b. Determine the molarity of either acid or base remaining after the reaction. c. Find the molarity if a 50.00 mL aliquot of this solution is diluted to 250. mL.

(8) Oxygen is produced by the reaction: 2KClO3 (s) →2KCl (s) + 3O2 (g)  The oxygen produced was collected over water. A sample of KClO3 produced 705 mL of oxygen saturated with water vapor at 20.0 °C where the vapor pressure of water is 17.54 mm Hg. The total gas pressure was 1.104 atm. What mass of KClO3 decomposed?

(9) How many grams of C2H2 must burn according to the equation below in order to heat 2.34 × 104 g of H2O from 25.0 °C to 35.0 °C? C2H2 (g) + O2 (g) →H2O (l) + CO2 (g), Δ = – 1212 kJ

HERE IS HOW THIS IS GOING TO WORK! IF YOU ANSWER THE QUESTIONS IWILL GIVE YOU THE 3K POINTS + MORE AFTER I REPOST IT.





2. The amount of heat involved in the synthesis of 1 mole of acompound from its elements, with all substances in their standardstates at 25*C, is called _________.


3. What is a valid unit for specific heat?


4. Use Hess's Law to find the heat of reaction in the examplebelow.

N2O4 (g) ----> 2NO2 (g)


Given that:

N2O4 (g) ----> N2 (g) + 2O2 (g) (Delta H =-9.7kJ)

2NO2 (g) ----> 2O2(g) + N2(g) ( Delta H= -67.7kJ)


5. Use Hess's Law to find the heat of reaction in the examplebelow. (Example doesn't exist btw.)


6. (Delta H) for the formation of rust (Fe2O3) is -826 kJ/mol. Howmuch energy is involved in the formation of 5 grams ofrust?


7. How many kilocalories of heat are required to raise thetemperature of 50g of aluminum from -5*C to 35*C? (Specific heat ofAluminum = 0.21 cal/g*C)


8.Calculate the (Delta H) for this reaction:


Zn(s) + Cu (2+ ion)(aq) ---> Zn(2+) + Cu(s)

(Delta H) for Cu(2+) = +64.4 kJ/Mol; (Delta H) for Zn(2+) = -152.4kJ/mol


9. The following equation shows the reaction that occurs whennitroglycerine explodes.

4C3H5O9N3 ----> 12CO2 + 6N2 + O2 +10H2O + 1725 Kcal


Is this reaction exothermic , endothermic, a combustion reaction ,or a combination reaction?


10. What does it mean for ammonia, (NH3) to have a (Delta H f) =-46 kJ/mol?

(for example: Define heat of formation. What does a negative heatof formation mean? what do the units of kJ/mol mean?)


11. What is the maximum amount of KCl that can dissolve in 500g ofwater?

(solubility of KCl is 34 g/ 100g of water at 20*C)


12.List the ways(operations) that can help make a substancedissolve faster in a solvent?


13. If a crystal added to an aqueous solution causes many particlesto come out of solution, the original solution was (saturate,unsaturated, supersaturated).


14. What is the number of moles of solute in 165 mL of a 0.82 Msolution?


15. What mass of NaCl is needed to make 350 mL of a 1.00 Msolution?


16. Colligative properties depend upon...


17. If one mole of each of these solutes in added to the sameamount of water, which solution has the highest boiling point?(glucose, aluminum sulfate, magnesium acetate, copper (I)chloride)


18. When an acid reacts with a base, what compounds areformed?


19. If the [H+] in a solution is 1x10^(-13) mol/L, what is the[OH-]?


20. If the [OH-] = 1x10^-6 mol/L, what is the pH of thesolution?


21. For a solution to be considered acidic what must be thehydrogen-ion concentration?


22. Which of the following represents a Bronsted-Lowry conjugateacid-base pair?

a) SO3(2-) and SO2 b) CO3(2-) and CO c) H3O and H2 d) NH4(+) and NH3


23. With solutions of "strong" acids and "strong" bases, the word"strong" refers to ...


24. What are the products of Al(OH)3 + H2CO3?


25.What is the concentration of hydrochloric acid if 5.0 mL of acidis neutralized by 30.0 mL of 2.00M sodium hydroxide.


26. At equilibrium, what is the rate of production of reactantscompared with the rate of production of products?


27. What is the equilibrium constant for the following reaction2SO3 ---> 2SO2 + O2


28. How does an increase in pressure affect the following reaction?2SO3 (g) --> 2SO2(g) +O2(g)


29.What stresses would shift the reaction to the right?

2SO3(g) ==> 2SO2(g) + O2(g)







30. The Keq of a reaction 4.9 x 10^(-7). Are products or reactantsfavored at equilibrium?


31. In which of these systems is the entropy decreasing?

a) air escaping from a tire b) snow melting c) a gas condensing d) salt dissolving inwater



32. If an atom is reduced in a redox reaction, what must occur toanother atom in the system?


33. Identify the oxidizing agent in the following reaction: 2Na + S---> Na2S


34. What are transferred in an oxidation -reductionreaction?


35. Give the oxidation number for each atom in KMnO4.


36. Which atom has a change in oxidation number of +4 in thefollowing reaction?

K2Cr2O7 + H2O + S ----> KOH + Cr2O3 +SO2


37. What is the oxidation number of sulfur in each of the following:

a. SO3 c.SO2(2-)

b. Na2SO4 d. S2O4 (2-)


38.Fe(3+) ----> Fe represents oxidation, reduction, orhydrolysis?


39. When the half reactions Br2+ 2e- -----> 2Br- and Na---->e- + Na(+) are combined the balanced redox equation is_____________________ ( WRITE the BALANCED REDOX eq)


40. To balance the oxygen and hydrogen for a redox reaction thattakes place in basic solution, it is necessary to use whichsubstance?


41. What particle completes this nuclear equation? 55/25 Mn + 2/1 H====> _____ +2 1/0 n


42. The half-life of tungsten-182 (182/74 W) is 1.1x10^(17) years.How long would it take for a 376.2 kg sample to decay until only123.0 grams remain?


43. After 3 days, the quantity of certain radioisotope is reducedfrom 13.6 grams to 1.9 grams. Calculate the half-life of theisotope.


44. What is the name of the compound having the formulaC8H18.


45. What is the name of the following compound:

O

//

CH3---CH2----CH---CH2--C

I \

CH3 OH


46. What is an isomer? Give an isomer of hexane (C6H14) and drawit's structure.


47. What is the name of the hydrocarbons with double covalentbonds?


48. Draw the stucture for 3-methylbutanoic acid.


49. Draw the structure for methylbenzene?


50. What is the name of the following compound:


Br

|

CH3----C-----CH3

|

CH3


Having trouble with thse questions. Please answer all questions correctly. Will provide a thumbs up.

1.Which of these equations is the balanced reaction between nitrous acid solution and solidmagnesium hydroxide ?

A.2NH3(aq) + MgOH (s) Mg(NH4)2(aq) + 2 H2O(l)

B.2HNO2(aq) + Mg(OH)2(s) Mg(NO2)2(aq) + 2 H2O(l)

C.2HNO3(aq) + Mg(OH)2(s) Mg(NO3)2(aq) + 2 H2O(l)

D.2HNO2(aq) + MgOH (s) Mg(NO3)2(s) + 2H2O(l)

2.Balance the following chemical equation:

C3H7OH(l) + O2(g)CO2(g) + H2O(g)

a. C3H7OH(l) + 4 O2(g)3 CO2(g) + 4 H2O(g)

b.2 C3H7OH(l) + 9 O2(g)6 CO2(g) + 8 H2O(g)

c.C3H7OH(l) + 5 O2(g)3 CO2(g) + 4 H2O(g)

d.C3H7OH(l) + O2(g)CO2(g) + H2O(g)

3.Which species would be considered a spectator ion based on the following equation?

Ba2+ + 2NO3− + 2Na+ + SO42- → BaSO4(s) + 2NO3− + 2Na+

SO42-

2NO3−

Ba2+

BaSO4

4.Barium sulfate is often ingested to aid in the diagnosis of GI tract disorders. The equation for its production is Ba2+ + SO42- → BaSO4(s). What type of equation is this?

A full equation

A net ionic equation

A total ionic equation

An oxidation-reduction equation

5.Which species is being reduced in this reaction?

CuO(s) + H2(g) Cu(s) + H2O(g)

H2O

CuO

Cu

H2

6.Which of the following is an oxidizing agent?

H2

NH3

O2

H2O

7.The following chemical equation,

HC2H3O2(aq) + KOH(aq) KC2H3O2(aq) + H2O(l),

is an example of a(n) _______ reaction.

a.oxidation-reduction and acid-base

b.acid-base

c.precipitation

d.oxidation-reduction and precipitation

e.oxidation-reduction

8.What substance is oxidized in the following reaction?

4HCl + MnO2 → Cl2 + 2H2O + MnCl2

a.Mn in MnO2

b.O in MnO2

c.Cl in HCl

d.H in HCl

9.What is the reducing agent in the following reaction?

4HCl + MnO2 → Cl2 + 2H2O + MnCl2

Cl2

MnCl2

HCl

MnO2

10.All redox reactions involve oxygen.

True

False

11.The term formula weight can be used with respect to which of the following?

A.ionic compounds

B.covalent compounds

C.both a and b

D.neither a nor b

12.What is the molecular weight of ibuprofen, C13H18O2?

A.206.3 amu

B.377.7 amu

C.29.0 amu

D.289.4 amu

13.The mass of an atom of 12C is exactly 12 atomic mass units. Which of the following describes a mole of 12C atoms?

A.a sample which weighs exactly 12 atomic mass units

B.a sample which contains 6.02 × 1023 atoms of 12C

C.both a and b

D.neither a nor b

14.The mass of an atom of 12C is exactly 12 atomic mass units. Which of the following describes a mole of 12C atoms?

A.a sample which contains 6.02 × 1023 atoms of 12C

B.a sample which weighs exactly 12.011 grams

C.both a and b

D.neither a nor b

15.What is the molar mass of water, H2O?

A.18.02 g

B.18.02 amu

C.17.01 g

D.17.01 amu

16.What is the molar mass of glucose, C6H12O6?

A.180.2 amu

B.180.2 g

C.60.05 amu

D.60.05 g

17.In the reaction 2H2O → 2H2 + O2, 2.0 mol water will produce how many grams of O2?

32

64

16

36

18.In the reaction 2CH4 + O2 → 2CO + 4H2, how many molecules of CO will be produced by the complete reaction of 1.60 grams of CH4?

3.01 × 1022

2.00

12.0 × 1023

6.02 × 1022

19.Suppose 2.43 g of magnesium is reacted with 3.20 g of oxygen: 2Mg + O2 → 2MgO. How many grams of MgO will be produced?

1.27

4.03

5.63

8.06

20.Which of the following conversion factors would allow one to calculate the amount of PbI2produced from a given amount of NaI in the following unbalanced reaction?

Pb(NO3)2 + Nal → Pbl2 + NaNO3

a.

b.

c.

d.

21.The unbalanced equation for the reduction of copper(I) sulfide with oxygen is given below. What mass of copper is produced from the reduction of 7.50 g Cu2S?

Cu2S(s) + O2(g) Cu(s) + SO2(g)

18.8 g

5.99 g

1.50 g

9.39 g

2.99 g

22.How many grams of aluminum oxide are produced by the complete reaction of 19.8 g aluminum with excess oxygen?

10.5 g aluminum oxide

37.4 g aluminum oxide

49.9 g aluminum oxide

74.8 g aluminum oxide

23.If 5 grams of CO and 5 grams of O2 are combined according to the reaction, which is the limiting reagent?

2CO + O2 → 2CO2

O2

CO and O2

CO2

CO

24.In an industrial process, nitrogen is reacted with hydrogen to produce ammonia. The percent yield of this particular process is 26%. How much hydrogen is needed to produce 4.8 kg ammonia?

1.5 kg

7.0 kg

0.85 kg

3.3 kg

25.A percentage yield greater than 100% has been reported in a scientific paper you are assigned to read. What would be a reasonable explanation for this?

a. The product was measured more than once.

b. It must be a typographical error since yields can't exceed 100%.

c. A lack of training of the professor who published the study.

d. Small measurement errors could have caused this to occur.

26.In an industrial process, nitrogen is reacted with hydrogen to produce ammonia. The percent yield of this particular process is 24.8%. How much hydrogen is needed to produce 3.7 kg ammonia?

1.8 kg

1.2 kg

4.4 kg

12 kg

2.7 kg

27.The following reaction has a percent yield of 90.5%. How many grams of carbon dioxide are produced from 78.5 g calcium carbonate via this reaction?

2 HNO3(aq) + CaCO3(aq) Ca(NO3)2(aq) + H2O(l) + CO2(g)

34.5 g

21.6 g

38.1 g

31.2 g

28.When gas molecules dissolve in liquids to form a saturated system, the process is usually

exothermic.

endothermic.

independent of the nature of the liquid.

temperature independent.

29.The reaction below would be considered.

CaCO3 + heat → CaO + CO2

an exothermic combination.

an exothermic decomposition.

an endothermic combination.

an endothermic decomposition.

30.The combustion of one mole of propane, C3H8, releases 531 kcal. How much heat is released by the combustion of 1.20 moles of propane?

A.584 kcal

B.690 kcal

C.443 kcal

D.637 kcal

31.The combustion of one mole of propane, C3H8, releases 531 kcal. How much heat is released by the combustion of 4.40 g of propane?

A.531 kcal

B.5.31 × 104 kcal

C.53.1 kcal

D.5.31 × 103 kcal

32.Metabolism of one mole of glucose, C6H12O6, releases 670 kcal. How much heat is released by the combustion of 0.300 moles of glucose?

A.201 kcal

B.2.41 × 103 kcal

C.186 kcal

D.2.23 × 103 kcal

33.Metabolism of one mole of glucose, C6H12O6, releases 6.70 × 102 kcal. How much heat is released by the combustion of 50.0 g of glucose?

A.201 kcal

B.2.41 × 103 kcal

C.186 kcal

D.2.23 × 103 kcal

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