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13 Dec 2019

1. Calculate the translational energy difference, in cm-1, between the 1,1,2 and the 1,1,3 energy levels of a 1-H 79-Br molecule confined to a cube with sides of 0.50 nm. The isotopic masses of H and 79Br are 1.008 and 78.918 g mol-1, respectively.


2. Calculate the vibrational energy difference, in cm-1, for the v=4 and v=3 states of 1-H 79-Br. The isotopic masses of H and 79-Br are 1.008 and 78.918 g mol-1, respectively. The HBr force constant is 410 N m-1.

3. Calculate the rotational energy difference in cm-1 between the l =5 and l =4 levels of a 1-H 79-Br molecule. The isotopic masses of H and 79-Br are 1.008 and 78.918 g mol-1, respectively. The HBr bond length is 0.141 nm.


4. Calculate the electronic energy difference in cm-1 between the n=3 and n=1 levels of a hydrogen atom.

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