Which of the following would you expect to have the highest boiling point? C8H18, CH4, C4H10, C2H6, C3H8

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Nestor RutherfordLv2

16 Dec 2019

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Entropy increases with increasing molecular complexity
Methane CH4; Sï¿½= 186.3J/mol-K
Ethane C2H6 Sï¿½= 229.6J/mol-K
Propane C3H8 Sï¿½= 270.3J/mol-K

What might you expect for the value of Sï¿½ for butane, C4H10?

Determine the number of moles of C in each sample. 1.) 3.3 mol CH4 2.) 0.152 mol C2H6 3.) 5.36 mol C4H10 4.) 23.6 mol C8H18

Use the normal boiling points
propane (C₃H₈) -42.1 °C
butane (C₄H₁₀) -0.5 °C
pentane (C₅H₁₂) 36.1 °C
hexane (C₆H₁₄) 68.7 °C
heptane (C₇H₁₆) 98.4 °C
to estimate the normal boiling point of octane (C₈H₁₈). Explain the trend in the boiling points.