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11 Dec 2019

One mole of each of the following coordination compounds is dissolved in one liter of water:

(a) [Co(NH3)6]Cl3; (b) K4[Fe(CN)6]; (c) [Ni(NH3)6]Cl2; and (d) [Ru(NH3)4Cl2]Cl.

Rank the solutions in order of increasing electrical conductivity.

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Sixta Kovacek
Sixta KovacekLv2
13 Dec 2019

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Related questions

Which of the following is most likely not an outer-sphereelectron transfer process?

A.[Cu(NH3)5Cl] + [Co(NH3)6]3+ --> [Cu(NH3)5Cl]+ +[Co(NH3)6]2+

B.[Cu(NH3)5Cl] + [Co(NH3)5Cl]2+ --> [Cu(NH3)4Cl2] +[Co(NH3)6]3+

C.[Fe(CN)6]4- + [RhCl6]2- --> [Fe(CN)6]3- + [RhCl6]3-

D.[Ni(NH3)5Cl]+ + [Co(NH3)5Cl]2+ --> [Ni(NH3)5Cl]2+ +[Co(NH3)5Cl]+


4. Compare the magnetic properties of [Fe(H2O)6]2+ and[Fe(CN)6]4-.

5. What change in magnetic properties (if any) can be expected whenNO 2-
ligands in an octahedral complex are replaced by Cl- ligands in ad6 complex?

6. Draw the orbital splitting diagram for the following complex andgive its
electron configuration: tetrahedral CoCl42-.

7. The complex ion PdCl42- is diamagnetic. Propose a structure forPdCl42-.

8. Explain the following differences in color:

A. [Cr(H2O)6]Cl3 is violet, whereas [Cr(NH3)6]Cl3 is
yellow.

B. [Co(H2O)6]2+ is pink, whereas tetrahedral
[CoCl4]2- is blue.

C. One of the following solids is yellow, and the other is
green: Fe(NO3)2·6H2O versus K4[Fe(CN)6·3H2O].
Indicate which is which and explain your reasoning.

Write a chemical equation representing what happens when each of the following water soluble Coordination Compounds dissolves in water.

a) [Cr(NH3)4Cl2]Cl

b) K2[PtCl4]

c) [Co(en)3](NO3)3

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