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18 Nov 2019
please answer the question 1.
CHEMISTRY 330 Spring 2017 Problem Set N2 A certain solid is placed in a equilibrium at 100 atm is pision and cylinder and to 50 atm and it then allowed to then suddenly dropped of arm expand thermally to a wolume E and pressure along the line P 575 (atm) 556.8 (atml t) V For this solid. KT 8.9 x ami u 00 atm and V 100 t. Find 1.03 x to K i, Aq for this change. 2. One mole of a certa van der Waal gas is ston cylinder initially at equilibrium placed in a pi volume 1.00 zero atm, at at ter a pressure of 23 and to system is placed in a vacuum jacket, and the pressure is suddenly which pressure the gas is allowed to to 10.0 E. At this point the of the gas is measured to suddenly increased to 1.63 atm A equilibrium the temperature to 1.00 and then the be 200K. The gas is then compressed isothermally and reversibly sample is heated at constant volume to Find for this cycle d b 0.0500 The van der Waals constants this as are a -2.50 mole an 3. The Tait Equation of state for a liquid may be written: Derive an expression for the isothermal compressibility of a uid that is described by the Tait equation Assume in the last step that V VJ. sketch the isothemai compressibility. In what limit does this equation approach the linearized equation of state? Assume A is independent of temperature and that BOT CT d c and d are constants. Determine the coefficient of thermal expansion for a Tait liquid, where A. c, d are constants, independent of temperature, sketch two or more isotherms on a P. diagram (V is the independent variable). Mark clearly the intercepts and asymptotes (i.e. ude b low (P 0) and high (P- large) pressure limits. Note a sketch need not be exact in the sense that you do not need to make any calculations only indicate the correct trends).
please answer the question 1.
CHEMISTRY 330 Spring 2017 Problem Set N2 A certain solid is placed in a equilibrium at 100 atm is pision and cylinder and to 50 atm and it then allowed to then suddenly dropped of arm expand thermally to a wolume E and pressure along the line P 575 (atm) 556.8 (atml t) V For this solid. KT 8.9 x ami u 00 atm and V 100 t. Find 1.03 x to K i, Aq for this change. 2. One mole of a certa van der Waal gas is ston cylinder initially at equilibrium placed in a pi volume 1.00 zero atm, at at ter a pressure of 23 and to system is placed in a vacuum jacket, and the pressure is suddenly which pressure the gas is allowed to to 10.0 E. At this point the of the gas is measured to suddenly increased to 1.63 atm A equilibrium the temperature to 1.00 and then the be 200K. The gas is then compressed isothermally and reversibly sample is heated at constant volume to Find for this cycle d b 0.0500 The van der Waals constants this as are a -2.50 mole an 3. The Tait Equation of state for a liquid may be written: Derive an expression for the isothermal compressibility of a uid that is described by the Tait equation Assume in the last step that V VJ. sketch the isothemai compressibility. In what limit does this equation approach the linearized equation of state? Assume A is independent of temperature and that BOT CT d c and d are constants. Determine the coefficient of thermal expansion for a Tait liquid, where A. c, d are constants, independent of temperature, sketch two or more isotherms on a P. diagram (V is the independent variable). Mark clearly the intercepts and asymptotes (i.e. ude b low (P 0) and high (P- large) pressure limits. Note a sketch need not be exact in the sense that you do not need to make any calculations only indicate the correct trends).