Calculate the pH for each of the following cases in the titration of 25.0 mL of 0.230 M pyridine, C_5H_5N(aq) with 0.230 M HBr(aq): before addition of any HBr after addition of 12.5 mL of HBr after addition of 22.0 mL of HBr after addition of 25.0 mL of HBr after addition of 29.0 mL of HBr