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87. Ethene (C2H4) can be halogenated by the reaction: C2H4(8) + X2(g) = C2H4X2(8) where X2 can be Cl2, Br2, or 12. Use the thermodynamic data given to calculate AH, AS, AG®, and K, for the halogenation reaction by each of the three halogens at 25°C. Which reaction is most spontaneous? Least spontaneous? What is the main fac- tor responsible for the difference in the spontaneity of the three reactions? Does higher temperature make the reactions more spontaneous or less spontaneous? Compound AH; (kJ/mol) Sº (J/mol ·K) 308.0 C2H4Cl2(g) -129.7 +38.3 C2H4Br2(g) C2H412(g) 330.6 347.8 +66.5

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Hubert Koch
Hubert KochLv2
30 Oct 2017
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