CHEM 101 Lecture Notes - Lecture 14: Pi Bond, Paramagnetism, Effective Nuclear Charge

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17 May 2016
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Recomposing existing valence atomic orbitals with linear combinations to create hybrid atomic orbitals. Yields bsd with proper orientation to create bonds that give rise to correct geometry. Combined an s and 3 p orbitals (px, py, pz) to get four sp3 orbitals. # hybrid orbitals used must actual steric number. % p is because there are 3 p orbitals for four total orbitals used. % s is because there is 1 s orbital used. Aos used s + p s + p + p s + p + p + p s + p + p + p + d s + p + p + p + d + d. Orbitals of atoms overlap constructively to form bonds. When the bond is symmetrical with respect to a rod going through it". Called a sigma bond or a sigma molecular orbital. In order to make a bond, some electrons get promoted upwards to hybrid orbitals.

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